南昌大学201上半年材料热力学重点题.docVIP

solution: Solution：,exothermic reaction For the reaction : Solution: (a) When the equilibrium is reached, T = 500(C = 773K at T=300(C=573K, Although the equilibrium PO2 is very low, kinetically the reaction is not favoured and reaction speed is very slow. So 300(C is not suitable at At T=800(C=1073K, lnPO2 =-22.2, PO2 =2.28(10-10 atm. At 800(C, if the equilibrium is reached, nitrogen can be of high purity level. However, at this high temperature , particles of Cu will weld together to reduce effective work surface. So it is n