环境工程毕业论文解析.docVIP

本科毕业设计(论文) 题 目: 高官能度蓖麻油基不饱和酯的合成及其应用研究 学 院: 化学工程学院 专 业: 环境工程 班 级: 1002051 学 号: 100205103 学生姓名： 范力 指导教师: 陈健强 职称: 讲师 二○一 四 年 五 月 十八 日 摘要 本文报道了利用高官能度的蓖麻油基马来酸半酯（Castor oil pentaerythritol glyceride maleates，简称COPERMA）来改性石油基不饱和聚酯树脂（Unsaturated Polyester Resin，简称UPR）。该蓖麻油基马来酸半酯通过醇解和马来酸酐化两步合成，并通过红外（FT-IR）、核磁（1H-NMR）和电喷雾质谱（ESI-MS）等表征其结构和可聚合C=C的官能度。1H-NMR结果表明，COPERMA产物上马来酸C=C的官能度较高（2.62）。该COPERMA产物与35 wt%的苯乙烯混合后，再与石油基UPR共混，制备出了部分替代的生物基不饱和聚酯树脂，并对该UPR/COPERMA树脂的物理性能、热性能和性能进行了研究。物理性能数据表明，所得生物基树脂适用于液态成型工艺，且与纯UPR相比线性收缩率低。另外，含有10 wt% COPERMA树脂的UPR/COPERMA树脂的热性能和机械性能与纯UPR的相当甚至更好。当COPERMA树脂增加至20 wt%时，拉伸强度和储能模量（35℃）有所下降，但并不像其他油脂基 UPR那样降其它性能如交联密度、玻璃化转变温度、拉伸和弯曲模量、冲击强度等，仍略有提高。 关键词：功能化蓖麻油 不饱和聚酯树脂 生物基改性剂 高官能度 结构塑料 Abstract A highly functionalized castor oil product mainly composed of castor oil pentaerythritol glyceride maleates (COPERMA) was employed to fabricate a partial biobased unsaturated polyester resin (UPR)through blending it with petroleum-based UPR. The COPERMA product synthesized was characterized by FT-IR, 1H-NMR, and ESI-MS to determine its possible structure and its functionality. The 1H-NMR results showed that the maleate C=C functionality of the COPERMA product was high (2.62). This highly functionalized product was then mixed with 35 wt% styrene before blending this mix with petroleum-derived UPR to prepare a new partial biobased UPR. Physical, thermal, and mechanical properties of the UPR/COPERMA resins were carefully studied. Physical properties data indicate that the resultant biobased resins are suitable for liquid molding process and had a less shrinkage than the neat UPR. Compared to the neat UPR, the cured UPR/COPERMA resins demonstrated comparable or even better thermal and mechanical properties when the content of COPERMA