碳纳米管超级电容器电极材料特性研究.docVIP

摘 要 碳纳米管arbon Nanotubes，CNTs)具有窄孔径分布、高比表面积利用率、高电导率和高稳定性为超级电容器电极材料而取向碳纳米管阵列(Carbon Nanotube ArrayCNTA)由于CNTs的独特的排列方式更加适合在超级电容器中的应用。在本论文中，MnO2电极MnO2复合电极和CNTA/MnO2复合电极1) 碳纳米管阵列电极在0.63mA电流下的比电容为4.34mF/cm2(大约8.68F/g)，其等效串联电阻为1.3?。 2) 二氧化锰电极在0.63mA电流密度下比电容为984.4mF/cm2(或82.0F/g)，其等效串联电阻分别为83.5?；其充放电曲线具有明显的近似三角形的对称性分布，表明电极反应的可逆性好。 3) 加入碳纳米管的MnO2电极(CNT/MnO2)的比电容高于MnO2电极，同时具有更小的内阻，说明MnO2电极中加入碳纳米管，会明显的降低MnO2电极的。 4)CM-60和CM-120在1.25mA下比电容分别为91.3F/g和67.8F/g，等效串联电阻分别为12.5?和20.9?。因此，二氧化锰的沉积时间过长不利于制备高容量和低内阻的复合电极，同时还会影响二氧化锰和碳纳米管阵列的附着性。 5) CNTA/MnO2复合电极的比容量大于MnO2电极，同时具备较低内阻，说明采用碳纳米管与二氧化锰的复合材料作为超大容量电容器的电极，既可以改善MnO2半导体的导电性能，又可以产生较大的法拉第准电容。超级电容器碳纳米管阵列复合电极材料电化学 Abstract Carbon Nanotubes (CNTs) are regarded as an ideal electrode material for supercapacitors, as a result of their narrow pore distribution, large specific surface area, excellent conductivity and high electrochemical stability. Compared with CNTs, Carbon Nanotube Arrays (CNTAs) are more suitable for application in supercapacitors, due to the unique arrangement of CNTs in CNTAs. In this dissertation, CNTA electrode, MnO2 electrode and CNT/MnO2 composite electrode, as well as CNTA/MnO2 composite electrode were fabricated, respectively, and their electrochemical properties were investigated in 0.5 mol/L Na2SO4 electrolyte . Through a series of experiments, the following conclusions were drawn： F/cm2(~ 8.68F/g) at 0.63mA, with Equivalent Series Resistance(ESR) of 1.3?. 2) MnO2 electrode, with high ESR of 83.5?, had specific capacitance of 984.4mF/cm2(~ 82.0F/g) at 0.63mA, and its charge and discharge curve illustrated an obvious symmetry of the approximately triangular distribution, presenting a good reversibility of the electrode reaction. 3) Compared with MnO2 electrode, MnO2 electrode with CNT(CNT/MnO2 electrode) showed higher specific capacitance and lower ESR. Therefore, by adding CNT, the ESR of MnO2 electrode was evidently reduced. 4) CNTA/MnO2 electrodes with 60min and 120min deposition time of MnO2 (labeled CM-60