AZ31B镁合金表面激光熔覆Cu_Ni合金层_崔泽琴.docx

第 20 卷第 9期中国有色金属学报2010 年 9 月Vol.20 No.9The Chinese Journal of Nonferrous MetalsSep. 2010文章编号：1004-0609(2010)09-1665-06AZ31B 镁合金表面激光熔覆 Cu-Ni 合金层崔泽琴 1, 2, 吴宏亮 1, 王文先 1, 2, 许并社 1, 2(1. 太原理工大学 材料科学与工程学院，太原 030024；太原理工大学 新材料界面科学与工程教育部重点实验室，太原 030024)要：针对镁合金表面耐磨性和耐蚀性差的问题，利用横流 CO2 激光器在 AZ31B 镁合金表面激光熔覆 Cu-Ni合金层，并利用光学显微镜(OM)、扫描电镜(SEM)和能谱分析仪(EDS)分析熔覆层与基体的结合界面特征以及显微组织和成分分布情况，测试合金层的显微硬度和耐蚀性。结果表明：合金层与基体结合良好，缺陷较少，但局 部存在不均匀的 Cu-Ni 富集区，且在其边缘区域的枝晶间均匀分布着 1~1.5 μm 的十字状 Laves 相；合金层的硬度 分布比较均匀，约为 75HV0.05，明显高于基体的显微硬度 45HV0.05；Cu-Ni 合金层比 AZ31B 镁合金基体的腐蚀电 位正移 317 mV，腐蚀电流降低 78 mA/cm2，耐蚀性也得到较大改善。关键词：AZ31B 镁合金；Cu-Ni 合金层；激光熔覆；耐磨性；耐蚀性中图分类号：TG 174.44文献标志码：ALaser cladding Cu-Ni alloy layer on AZ31B magnesium alloyCUI Ze-qin1, 2, WU Hong-liang1, WANG Wen-xian1,2, XU Bing-she1,2(1. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China;2. Key Laboratory of Interface Science and Engineering in Advanced Materials of Ministry of Education,Taiyuan University of Technology, Taiyuan 030024, China)Abstract: To improve the wear resistance and corrosion resistance of the surface of magnesium alloy, the laser alloying experiment was carried out on the AZ31B magnesium alloy with pre-placed Cu-Ni powder using transverse flow CO2 laser. The microstructures, interface features and composition distribution of laser cladding layer were studied through OM, SEM and EDS. The results show that the Cu-Ni cladding layer and the substrate achieve a good metallurgical bonding without obvious defects. But there is uneven local Cu-Ni-rich region, and cross-like Laves phases with size of 1?1.5 μm evenly distribute between dendrites and in their edge regions. The microhardness of Cu-Ni cladding layer is more evenly distributed, about 75HV0.05, significantly higher than the matrix hardness (45HV0.05). Compared with AZ31B magnesium alloy, the corrosion potential of Cu-Ni alloy layer is shifted by 317 mV and corrosion current is reduced by 78 mA/cm2.Key words: AZ31B magnesium alloy;