30kta邻苯二甲酸酐车间氧化工段初步设计毕业设计说明书.docVIP

学 号：201007010214 HEBEI UNITED UNIVERSITY 毕业设计说明书 GRADUATE DESIGN 题目：30kt/a邻苯二甲酸酐车间氧化工段初步设计 学 院： 化学工程学院 专 业： 化学工程与工艺 班 级： 化工 2 班 姓 名： 唐亮 指导教师： 陈红萍 2014年 月 日 本设计为年产kt/a邻苯二甲酸酐氧化工段的设计。从原料角度看，工业上生产邻苯二甲酸酐的工艺主要有萘催化氧化法和邻二甲苯氧化法。随着石油化工的高速发展,邻二甲苯的产量越来越高，价格也越来越便宜所以，邻二甲苯逐渐取代了萘。BC-239型催化剂，反应管规格为：φ32×3.5，长3m，装催化剂高度为2.5m。并计算得出列管式固定床反应器的内径Di=5000mm，实际装催化剂的管根数为：12340根。通过能量衡算计算出设备的热负荷，并对其进行了计算选型，对车间布局进行了设计。确定了非工艺条件。利用AutoCAD绘制完成了带控制点的工艺流程图，反应器结构图以及车间平面布置图。 关键词: 苯酐；BASF；固定床反应器；流程图 ABSTRACT This paper mainly introduce the design of phthalic anhydride oxidation section, whose annual production is 30kt/a. In the view of raw material, there are two methods for the production of phthalic anhydride in industry, oxidation of naphthalene and oxidation of o-xylene oxidation. For this reason, it provide the prerequisites of the production of phthalic anhydride by oxidation of o-xylene. By comparing each craft, this design chosen international advanced BASF (benzene bitter wine technique of production), arranges in order the tubular fixed bed reactor, selected the BC-239 catalyst,the specification of the reaction tube is: φ32×3.5, length 3m, the height for installng the catalyst is 2.5m．so we calculated the inside diameter of row tubular fixed bed reactor Di=5000 mm, the actual number of attire catalysts tube is 12340．Figures out equipments heat load according to the law of energy conservation, also calculated and chosen the type of it, and designed the layout of the workshop. Has determined the non-technological conditions and completed the belt control point flow chart using the AutoCAD plan, the reactor structure drawing as well as the workshop floor-plan. Keywords：pothalic anhydride；BASF；process；fixed bed reactor 目录 摘 要 I ABSTRACT I 引　言 1 第一章 综 述 3 1.1苯酐的基本性质 3 1.2苯酐的用途及其应用前景 3 1.3苯酐的生产发展历程 4 1.4苯酐市场需求状况 5 1.5苯酐技术的进展及发展方向 5 1.6苯酐工艺