毕业设计(论文)-Al离子掺杂Mn3O4基膜片温敏材料的制备与性能研究1.docVIP

安徽建筑工业学院本科生毕业设计 Al离子掺杂Mn3O4基膜片温敏材料的制备与性能研究 PAGE 32 PAGE 33 摘 要 本文研究了FeMnNi1-xAlxO4的制备、结构与性能。利用塑性成型法成型，以高温固相法制备FeMnNi1-xAlxO4。用Y2000 Automated x-ray Diffractometer system对样品的相结构进行分析。用型号为SEMI-VICKERS HARDNESS TESTER HV-10的维氏硬度仪测量样品的硬度。用自制的设备测量样品的温阻特性。结果表明，所掺杂的氧化铝与FeMnNiO4形成了固溶体；已制备好的NTC热敏电阻电阻率和绝对温度的倒数之间的关系为线性关系，显示了所制备材料的负温度系数特性；随着Al2O3掺量的增加，样品的B值逐渐增加，且老化后各样品的B值增大，对温度变化的敏感性增强；在热敏常数B为定值时，NTC的电阻率随着氧化铝含量的增加而增加。 关键词 FeMnNi1-xAlxO4 负温度系数热敏电阻 塑化剂 固溶体 B值  Abstract In this paper, the preparation、structures and properties of FeMnNi1-xAlxO4 have been discussed. Using plasticizer to help shape and high temperature solid state reaction to prepare FeMnNi1-xAlxO4.?With Y2000 Automated x-ray Diffractometer system , the phase structure of the samples were analyzed.?The hardness of the sample was measured by the model SEMI-VICKERS HARDNESS TESTER HV-10 Vickers hardness.?Using homemade equipment to analyze temperature and resistance characteristics of the sample.?The results show that the alumina and other oxides formed solid solution; The relationship between the resistivity of the sample and the reciprocal of absolute temperature is linear, which just showed the negative temperature coefficient characteristics of NTC?; With the Al2O3 content increasing, the value of B gradually increased, and after aging, the value of B also increaseed,which showed the temperature sensitivity of the sample was more strength; When the thermal constant B is constant, NTC resistivity increased with?alumina content increases. Key words: FeMnNi1-xAlxO4 NTC plasticizer solid solution the thermal constant B  目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc263852672 摘 要 PAGEREF _Toc263852672 \h I HYPERLINK \l _Toc263852673 Abstract PAGEREF _Toc263852673 \h II HYPERLINK \l _Toc263852674 目录 PAGEREF _Toc263852674 \h III HYPERLINK \l _Toc263852675 第一章 综述 PAGEREF _Toc263852675 \h 1 HYPERLINK \l _Toc263852676 1．1负温度系数(NTC)热敏电阻材料体系 PAGEREF _Toc263852676 \h 1 HYPERLINK \l _Toc263852677 1．1．1