壓裂液对煤结构的影响.docVIP

压裂液对煤结构的影响 摘要 本文运用溶剂抽提的方法研究了压裂液对煤结构的影响。以韩城煤为研究对象，分别浸泡在SFA，SFB，F108（浓度0.5%）三种压裂液中，且浸泡不同时间。在不同时间段进行不同溶剂的萃取及反萃取，对萃取产物及残渣进行IR表征。结果表明：混合溶剂的萃取率远大于纯溶剂，且混合溶液的萃取条件比较容易实现；其中F108压裂液对煤样的三种溶剂的萃取率有增大的效果，并且压裂液浸泡对总萃取率有增大的作用。三种不同煤样的红外分析结果说明压裂液对煤中官能团种类、小分子化合物的相对含量有一定的影响。两种压裂液浸泡煤样CS2/NMP萃余煤的单一溶剂萃取物中检出较多的含氧、含氮化合物和酯类化合物，说明压裂液对煤的表面化学结构有较大影响。 关键字：压裂液，韩城煤，溶剂抽提，FTIR，GC/MS Abstract In this paper, the influence of fracturing fluid on coal structure is investigated by the solvent extraction. Hancheng coal was soaked in three different fracturing fluids(SFA，SFB，F108) with different times. Solvent extraction and stripping are conducted in different time periods. IR was used to characterize the extraction and residue. The results showed that: extraction rate of the mixed solvent is much larger than the pure solvent, and extraction conditions of the mixed solution are relatively easy to implement; extraction rate of F108 fracturing fluid was higher than anther two fracturing fluids, and to the total extraction rate of the coal soaked in fracturing fluid was enhanced. Infrared analysis of the fracturing fluid about three different coal samples was conducted. The results indicated that it has a certain impact on the relative content of small molecule compounds and the types of functional groups in coal. The coal soaked in two fracturing fluids was extracted in CS2/NMP followed by a single solvent. The extract of the later solvent contains more oxygen, nitrogenous compounds and ester compounds, indicating that the fracturing fluid has great influence on the chemical structure of coal surface. Keywords: fracturing fluid; Hancheng coal; the solvent extraction; FTIR; 引言 压裂是一种利用压力将 HYPERLINK /view/66093.htm \t _blank 地层压开，形成裂缝，再用 HYPERLINK /view/2474555.htm \t _blank 支撑剂将裂缝支撑起来，以达到减小流体流动阻力增产、增注的措施。其中所用的支撑剂也称为压裂液，是压裂作业中用到的工作液，是用多种添加剂按一定比例配成的非均质不稳定的化学体系。压裂液一般可分为两类：A油基压裂液（油冻胶压裂液，稠化油压裂液，油基泡沫压裂液,油包水压裂液）；B 水基压裂液（水冻胶压裂液，水包油压裂液，水基泡沫压裂液，稠化水压裂液）。 在煤层气开采过程中，必须使用不同的压裂液，使煤层气的开采变得更容易，而这些压裂液会对煤结构产生影响，主要表现在煤中官能团，小分子化合物