2014-现代化学研究方法和技术概述.ppt

Work out example B1g B2u D4h ? ?i(x, y, z) ?j d? In D4h, z ? A2u and x , y ? Eu B1g? A2u ?B2u = A1g B1g? Eu ?B2u = Eg Thus, ? ? ?* transition allowed with z polarization. Interpretations of d – d transition in metal complexes. 1. Mixture of d and p orbitals of the same symmetry species. In Td symmetry, both p orbtils (px, py, pz) and d orbtials (dxy, dxz and dyz) belong to the same irreducible representation T2. Therefore, they are mixing in the t2 a of Tetrahedral metal complex. So, the transition e ? t2 is not strictly d – d. For example, [Co(H2O)6]2+, pink; [CoCl4]2? deep blue;