05X射线衍射原理-1题库.ppt

* 衍射方向 小结 衍射矢量方程、布拉格方程+反射定律、厄瓦尔德图解、劳埃方程+协调方程作为衍射必要条件都是等效的。 衍射矢量方程更具有普遍性。 * 思考题： α-Fe属立方晶系，点阵参数a=0.2866nm。如用CrKα　X射线（λ=0.2291nm）照射，试求（110）、（200）及（211）可发生衍射的掠射角。 * Smaller Crystals Produce Broader XRD Peaks * When to Use Scherrer’s Formula Crystallite size 1000 ? Peak broadening by other factors Causes of broadening Size Strain Instrument If breadth consistent for each peak then assured broadening due to crystallite size K depends on definition of t and B Within 20%-30% accuracy at best Sherrer’s Formula References Corman, D. Scherrer’s Formula: Using XRD to Determine Average Diameter of N