第3部分UVfinal学习课件.pptVIP

第3章 紫外-可见光谱(Ultraviolet/visible spectroscopy) 3.1 Background Basics of UV Light Absorption Ultraviolet/visible spectroscopy involves the absorption of ultraviolet/visible light by a molecule causing the promotion of an electron from a ground electronic state to an excited electronic state. Ultraviolet/Visible light: wavelengths (l) between 190 and 800 nm. Peak Broadening UV absorptions are generally broad because vibrational and rotational levels are superimposed on top of the electronic levels. Peak broadening 电子跃迁规则 自旋多重性 Pauli原理,同一轨道上2个自旋电子方向相反,自旋量子数 s=±1/2, 自旋多重性S = 2s