本科毕业设计—焦炉煤气中氨回收工艺设计.docVIP

22000 m3/h焦炉煤气中氨回收工艺设计 The Process Design of Ammonia Recovering from 22000m3/h Coke Oven Gas 目录 摘要 1 Abstract. II 引 言 1 第一章 综述 2 1.1氨的来源 2 1.2氨的回收 2 1.3氨的回收工艺 2 1.3.1浓氨水工艺 2 1.3.2弗萨姆(Phosam)无水氨法 3 1.3.3氨分解工艺 3 1.3.4硫铵工艺 3 1.4鼓泡式饱和器法 6 第二章 工艺流程 7 2.1鼓泡式饱和器法回收氨的工艺流程 7 2.2饱和器法回收氨的影响因素及控制 8 2.2.1预热器后的煤气温度 8 2.2.2母液温度 9 2.2.3母液酸度 10 2.2.4母液的循环搅拌 10 2.2.5母液中的结晶浓度（晶比） 11 2.2.6结晶槽中结晶层的厚度 11 2.2.7离心分离和水洗 11 2.2.8沸腾干燥器的操作 12 2.2.9母液的净化处理 13 第三章 物料衡算和热量衡算 14 3.1饱和器的物料衡算 14 3.1.1饱和器的氨平衡和硫酸用量计算 14 3.1.2饱和器的水平衡计算 15 3.1.3饱和器内最低温度和最适宜温度的确定 16 3.2饱和器的热量衡算 17 3.2.2输出热量 20 第四章 饱和器的计算 23 结 论 27 致 谢 28 参考文献 29 附录 22000m3/h焦炉煤气中氨回收工艺设计 摘要：氨是一种重要的工业原料，对氨的回收能够减少资源浪费，增加经济效益，此外氨对环境危害极大，不利于环境保护。因此将氨回收具有重要的意义。本设计是采用饱和器法经过设计计算，该设计工艺基本可完成既定设计任务，即完成00m3/h焦炉煤气中氨回收的工艺目标和水平。设计中对进行了物料衡算和热量衡算。最终结果符合工艺条件，达到设计要求。～，饱和器后煤气含氨量为0.03g/m3。煤气预热温度℃，饱和器出口煤气中水蒸气分压7.43kPa，母液温度℃，得到硫酸铵产量kg/h，而硫酸的消耗量为kg/h。根据工艺要求，对进行了The Process Design of Ammonia Recovering from 22000m3/h Coke Oven Gas Abstract：Ammonia is an important industrial raw materials, recycling of ammonia reduce waste of resources and increase economic benefits, in addition to ammonia great harm to the environment is not conducive to environmental protection. Therefore, the ammonia recovery is significant. This design is the use of bubbling ammonia saturator law by the reaction of ammonium sulfate and sulfuric acid process for recovery of ammonia. After the design calculations, the design process can be completed given the basic design tasks to complete 22000m3/h COG ammonia recovery process goals and level. Design for Bubble saturation were carried out mass balance and heat balance. The end result meets conditions, to meet the design requirements. Ammonia gas content of 1% to 1.5%, the amount of ammonia gas saturator 0.03g/m3. Gas preheating temperature 65.3℃, outlet gas saturated water vapor partial pressure 7.431kPa, liquor suitable temperature 53.6℃, obtain ammonium sulfate production 735.768kg/h, while the consumption of sulfuric acid is 700.32kg