铁炭法与过氧氢投加比例.docVIP

本帖最后由 cdpulin 于 2010-5-5 17:00 编辑 铁炭微电解—Fenton试剂联合氧化深度处理印染废水的研究摘要：采用铁碳微电解—Fenton联合氧化技术对印染废水生化处理的出水进行深度处理。通过正交试验考察了pH值、H2O2投加量、铁碳体积比、反应时间对处理效果影响的大小，分别为pH〉铁碳体积比〉H2O2用量〉反应时间。并通过单因素实验确定在最佳反应条件下：pH为2~3，H2O23.2mL/L，铁碳体积比为1：1，反应时间为90min，COD的去除率能够达到90%以上，色度去除率为99%，盐度去除率为64%。各项指标均达到了印染水的回用指标。关键词：铁碳微电解；Fenton试剂；印染废水；深度处理。中图分类号：X703.1? ?? ?? ?? ?? ?? ?? ?? ?? ?文献标识码：AStudy on advanced treatment of printing and dyeing wastewater by joint oxidation technology of iron-carbon micro-electrolysis and? ?? ?? ?? ?? ? Fenton reagentsJIANG Xing-hua1，LIU Yong-jian2，JIN Liang-ji1(1. Department of Environmental Science and Engineering,Suzhou??Univ.of Science and Technology. Suzhou 215011 China; Department of Chemical and Biological Engineering,Suzhou??Univ.of Science and Technology. Suzhou 215011 China;)Abstract? ?Advanced treatment of printing and dyeing wastewater by joint oxidation technology of iron-carbon micro-electrolysis and Fenton reagents was studied. Orthogonal array experiments was designed to study the different degree of??impact on the treatment effection.The result was pH 〉volume ratio of iron and carbon 〉H2O2 dosage〉reaction time. It is found by single-factor experiments that the best experimental conditions are as follows: pH is 2to 3，H2O2 dosage is 3.2mL/L，volume ratio of iron and carbon is1:1，reaction time 90min.In this condition,the removal rates of COD ，chroma and salinity can reach 91%,99% and64% respectively.Each met the reuse requirements of printing and dyeing water.Key words: iron-carbon micro-electrolysis；Fenton reagents；printing and dyeing wastewater；advanced treatment.引言? ? 印染行业近几年来需水量和排水量大幅增长(1)。对印染废水的深度处理并进行回用，既能够减少环境污染又能缓解水资源短缺的危机（2）。印染废水二级出水色度高，COD难以去除，造成这种状况的因素除了生物处理负荷低于实际要求的COD负荷以外，还因为废水中存在大量的难以被生物降解的各种复杂的有机物（3~4），如苯胺、硝基苯、偶氮染料等。因此印染废水的深度处理主要是对COD和深度的去除(2)。此外，还应防止无机盐的积累。铁碳微电解，于上世纪70年被前苏联最先应用于印染废水的处理中在具有使用范围广、处理效果好、使用寿命长、成本低廉及操作维护方便的特点（5）。，目前已经被广泛应用于印染（3）、农药（6~7）、制药（5）、制浆造纸（8~9）等废水处理中。作者利用铁碳微电解—Fenton试剂联合氧化技术对印染废水的二级出水进行深度处理，使得出水达到了