《毕业设计(论文)－纳米阵列电极有机太阳能电池的制备》.doc

PAGE 18 纳米阵列电极/有机太阳能电池的制备 摘要 太阳能电池有着广阔的应用前景，而决定太阳能电池应用价值的关键因素是其制备材料对太阳能的转换率。由于氧化锌和聚噻吩特殊的结构和性质，使得它们在太阳能电池的制备上有着极大的应用。本文通过详细论述氧化锌和聚噻吩不同的制备过程，并用扫描电子显微镜对样品形貌进行了表征。分析了不同前驱液浓度和不同PH值对氧化锌纳米棒生长状况的影响以及不同温度对聚噻吩电导率的影响。分析发现前驱液浓度越大，长出的氧化锌纳米棒直径越大；在合适的高PH值环境下，氧化锌纳米棒生长速度明显快于其他样品，且对生长条件要求不高，非常适合用于氧化锌纳米棒大面积制备。而温度越高，聚噻吩的电导率则约低。 关键词：太阳能电池，氧化锌，聚噻吩 Abstract Solar cells have broad application prospects，and the key factor to the solar cell application value is the conversion rate of its preparation materials. For ZnO and polythiophene special structure and properties,they have great application in the preparation of solar cells.This article through the detailed discussion on ZnO and polythiophene different preparation process,and the sample morphology are characterized by scanning electron microscope.Analyzes the effect on ZnO namo-rod growth situation of different precursor liquid concentration and different PH value and the effect on polythiophene conductivity of different temperature.The results shows that the higher the concentration of precursor liquid,the larger the diameter of ZnO namo-rod;Under a suitable high PH value, ZnO nano-rod will have a fast growth rate even in loose environment,so it is vary suitable for large-scale preparation of ZnO nano-rod arrays.And the higher the temperature,the lower the conductivity of polythiophene. Key words:Solar cells;ZnO;polythiophene 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc230438046 摘 要 1 HYPERLINK \l _Toc230438047 Abstract 1 HYPERLINK \l _Toc230438049 第一章 前言 4 HYPERLINK \l _Toc230438050 1 研究目的和意义 4 HYPERLINK \l _Toc230438051 2 基本原理 4 HYPERLINK \l _Toc230438052 2.1 纳米阵列电极的基本原理 4 HYPERLINK \l _Toc230438053 2.2 太阳能电池的基本原理 6 HYPERLINK \l _Toc230438055 第二章 ZnO纳米棒的制备 7 HYPERLINK \l _Toc230438056 1 溶胶-凝胶法 7 HYPERLINK \l _Toc230438057 2 电化学沉积法 7 HYPERLINK \l _Toc230438058 3 喷雾热分解法 8 HYPERLINK \l _Toc230438059 4 金属有机物化学气相沉积法 8 HYPERLINK \l _Toc230438061 5 脉冲激光沉积法 8 HYPERLINK \l _Toc230438062 6 分子束外延法 9 HYPERLINK \l _Toc2304