谭天恩 化原理题解(1~6).docVIP

谭天恩 化工原理题解(1~6) 本文由z461014237贡献 doc文档可能在WAP端浏览体验不佳。建议您优先选择TXT，或下载源文件到本机查看。 化工原理题解 1-1 解： ρ = pM RT p=450mmHg，M=29kg/kmol,R=8.314kJ/(kmol·K),T=233K ρ= 450 × 29 × 101.3 = 0.898kg / m 3 8.314 × 233 × 760 1-2 解：真空度=大气压-绝对压力 即：760-738=655-真空度 真空度=633mmHg 1-3 解： P = P水 + P油 = ρ 水 gh 1 + ρ 油 gh 2 = 1000 × 0.52 × 9.8 + 3.46 × 9.8 × 916 = 36300Pa（表压） = 271mmHg（表压） = 3.69mH 2 O（表压） 1-4 解： P下 = P上 + ρgh （58 ? 42） 10 3 = 1000 × 9.8(?Z ? 0.55) × ?Z = 2.18m 1-5 解 752mmHg=100200Pa=100.2kPa 绝压=大气压-真空度=100.2-83.4=16.8kPa 表压=-真空度=-83.4 kPa P = ρgh H= ?P 83.4 = = 8.51m ρg 1000 × 9.8 即：液柱高度为 8. 51m。 1-6 解 Pbottom = Ptop + ρ gh ， ρ = Pbottom + Ptop pM ，p = RT 2 Ptop = Pbottom 2000RT ? Mgh 2000RT + Mgh 2000 × 8.314 × 293 ? 9.807 ×102 × 4 × 29 2000 × 8.314 × 293 + 9.807 × 102 × 4 × 29 Ptop = 101.3 × 103 × = 96.5869 × 103 Pa =724.64mmHg PTop 又解 pM RT pM dP =?P = P2 ? P = ? gdh 1 RT Pt dP 102×4 M =?∫ ∫Pb P 0 1000RT gdh 408Mg ln P Pb = Pt 1000RT P 408Mg ln b = Pt 1000RT P2 = P ? ρ gdh, ρ = 1 Pt = Pb e 408Mg 1000RT ? 408× 29×9.807 1000×8.314×293 P2 dh P1 h PBottom = 101.3 × 103 × e = 96587.80Pa = 96.5878kPa A 1 2 3 4 5 6 7 8 B C D Ptop=PbottomEXP(-MgH/1000RT) Ptop=PbottomEXP(-MgH/1000RT) Ptop 96.5878 kPa = Ptop 96.5878 kPa = Pbottom 101.3 Pbottom 101.3 29 M M 29 408 H H 408 293 T T 293 层高 层高 4 4 层数 层数 102 102 A 1 2 3 4 5 6 7 B C D Ptop=PbottomEXP(-MgH/1000RT) Ptop=PbottomEXP(-MgH/1000RT) Ptop 96kPa 96kPa Ptop Pbottom 101.3 Pbottom 101.3 29 M M 29 408 H H 408 293 T T 293 层高 层高 4 4 层数 102 层数 102 = = 1-7 解 P = PA + ρ H2 O gh1 1 P = P2 + ρ Hg gR 1 1 A H 2O R1 h1 2 B 4 h2 R2 3 Hg P3 = P2 + ρ H 2O g(h 2 -h1 +R 1 ) P3 = PB + ρ H 2O g(h 2 -R 2 ) + ρ Hg gR 2 所以 1 PA = P2 + ρ Hg gR1 ? ρ H 2O gh1 PB = P2 + ρ H2 O g(h 2 -h1 +R1 ) ? ρ H 2O g(h 2 -R 2 ) ? ρ Hg gR 2 PAB = PA ? PB = ( P2 + ρ Hg gR 1 ? ρ H 2O gh