第2章均相反应动力学基础方案.pptVIP

第2章 均相反应动力学基础 纪红兵 中山大学化学与化学工程学院 Tel:jihb@mail.sysu.edu.cn 反应速率表示方法 The Rate Expressions The Rate Expressions Suppose a single-phase reaction A P The most useful measure of rate for A is then 均相反应速率定义：单位时间内，单位体积反应混合物中某一组分i的反应量（或生成量）。 Caution 1 2 (-rA) 为一整体符号，恒为正值 Suppose a single-phase reaction aA+bB pP+sS The rates of all materials are related by Caution 3 According to the rate equation Caution 4 Or For the ideal gases where Caution 5 The rate of reaction in its various forms is defined as follows Based on unit volume of reaction fluid Based o