《铁基非晶粉末在污水净化中的应用毕业论文》.docx

铁基非晶粉末在污水净化中的应用摘要在有机废水处理行业，零价铁作为一种价格低，应用工艺简单的材料，已经早已应用到了该领域中。但是铁粉极易被腐蚀的缺点也显而易见，难以被二次利用，而铁基非晶作为一种结构非晶的零价铁，相比于零价铁，具有更好的抗腐蚀性，而且金属非晶本身的优异性能也使其具有更大的应用前景。本论文先做了铁粉与铁基非晶粉末在处理有机废水（甲基橙）时的对比实验。实验结果表明，非晶粉末在降解甲基橙溶液时比铁粉具有明显的优越性，而且非晶粉末比球磨非晶和球磨退火非晶的降解效率更好。之后通过改变反应温度、粉末投加量以及甲基橙溶液的初始PH值研究了影响铁基非晶降解甲基橙溶液的影响因素。实验结果表明，反应温度越高，溶液初始PH值越低，非晶粉末投加量越多，降解反应进行的越快，降解的效率也越高。反应温度越高，反应物分子的平均动能增大从而加快反应速率，加快非晶粉末降解甲基橙溶液。非晶粉末投加量的增加可能增加了非晶粉末表面的活性位点，从而为反应提供更多的机会，提高了非晶粉末降解甲基橙溶液的降解效率。PH值对降解反应有着较大的影响，不仅加快了降解反应速率，而且在PH值足够低时，还改变了甲基橙染料的组成结构，使降解反应更容易发生。关键词：铁粉，铁基非晶，偶氮染料，甲基橙Application of Fe-based amorphous powders in sewage purificationAbstractIn organic wastewater treatment industry,zero-valent iron(ZVI) as a lowprice,simple materials application technology,has already used in this fields.But the corrosion of iron powder are obvious,so it is hard to be secongary use.Iron-based amorphous as an amorphous structure of zero-valent iron,compared with zero-valent iron,with better corrosion resistance,and the excellent properties of the amorphous metal itself make it has greater prospect. This paper have performed a contrast experiment between Iron powder and iron-based amorphous powder in the treatment of organic wastewater (methyl orange).The result showed that the amorphous powder on the degradation of methyl orange solution has better effect than the iron powder, and the amorphous powder has the better effect than milling amorphous and mlling annealing amorphous. By changing the reaction temperature, powder add quantity as well as the the initial PH of solution studied the influence factors of the iron-based amorphous degradation of methyl orange solution.The experiment results show that the initial solution PH is lower, amorphous powder dosing quantity is more, and degradation reaction is faster, the degradation efficiency is higher. The reaction temperature is higher, average kinetic energy of reactant molecules has been increased so as to speed up the reaction rate. Increasing Amorphous powder dosage may build up