西工大fundementals meterials and engineers 复习题知识点.docVIP

复习题 1、On the basis of crystal structure, using the following equation and values of parameters, compute the theoretical density for sodium chloride (NaCl). How does this compare with its measured density? Measured density of NaCl is 2.16 g/cm3. Theoretical density formula: Solution: According to the structure of NaCl, each unit cell consist of 4 NaCl formula units. Therefore, n’=4. Furthermore, since the unit cell of NaCl is cubic, therefore, VC=a3, a being the edge length of the unit cell. Again with referred to the structure of NaCl, a=2rNa++2rCl- Thus, VC=(2rNa++2rCl-)3 U