配位化学【双语版】chapter1.pptxVIP

Chapter 1 IntroductionThe origin of coordination chemistry 1. Early coordination compounds 2. Werner - the father of coordination chemistryAlfred Werner received the Nobel Prize in 1913 for his coordination theory of transition metal-amine complexes. At the start of the 20th?century, inorganic chemistry was not a prominent field until Werner studied the metal-amine complexes such as?[CoNH36Cl3]?--?Werner compound.Proposed Structure of Cobalt Amonia Complexes from Number of Ionized Chloride Solid ColorIonized Cl-?Complexformula? CoCl36NH3? ?Yellow[CoNH36]Cl3 CoCl35NH3? Purple[CoNH35Cl]Cl2? CoCl34NH3 Green trans-[CoNH34Cl2]Cl CoCl34NH3? Violetcis-[CoNH34Cl2]ClA consequence of the?octahedral model was that optical isomers should be possible for certain types of complexes. It was with the experimental work on coordination complexes dealing with molecular conductance.Conductivity Measurements?Reveal the Charge and the Ionic Character of Coordination CompoundsIt has been predicted that the complex CoNH2CH2CH2NH22ClNH3]2+? NH2CH2CH2NH2? en and [CoNH34Cl2]?should exist in two forms, which are?mirror images?of each other. Werner isolated solids of the two forms, and structural studies confirmed his interpretations.Because of the prevailing view that optical activity was integrally related to?C?atoms, Werner decided that it was necessary to prepare a completely inorganic complex i.e.,no C atoms to prove that inorganic complex can also exist as?mirror-image isomers.The absolute configuration of [Coen3]3+Coordination chemistry?is the study of compounds formed between metal ions and other neutral or negatively charged molecules. A?coordination complex?is the product of a Lewis acid-base reaction in which neutral molecules or anions called?ligands bond to a central metal atom or ion by coordinate bonds.For example: A complex is AgNH32+, formed when Ag+?ions are mixed with neutral ammonia molecules. ?Ag+?+ 2 NH3?AgNH32+ A complex AgS2O323-?is formed between silver ions and neg