配位化学【双语版】Chapter 3.pptx

Chapter 3 Spectrum of Coordination CompoundIntroduction ?When a beam of electromagnetic radiation of intensity lo?is passed through a substance, it can either be absorbed or transmitted, depending upon its frequency and the structure of the molecule. ?The frequency of the absorbed radiation is related to the energy of the transition by Plancks law:Efinal?- Einitial?= E = hν = hc/l . (1) if the frequency of radiation (or l ) satisfy the Planck expression, then the radiation can be absorbed. (2) if not, then the radiation will be transmitted.A plot of the frequency of radiation vs. some measure