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2016-10-21 Published: 22 August 2016 INTRODUCTION 相较于共价键交联的自修复凝胶，物理作用交联的水凝胶不需要外界的额外刺激就可以自修复。 相对于合成材料而言，本文中制备的材料毒性小，而且制备简单。 钙离子作为交联剂更适合于人体。 本文制备的材料是通过加热牛血清蛋白使得构想改变，引发纳米聚集，再利用钙离子进行交联得到蛋白质水凝胶。并且到目前为止还没有人制备这种在室温条件且在生理条件下交联的蛋白质水凝胶。 Results Figure 1. The self-healing protein hydrogel system. (a) The proposed gelation process. (b) The schematic of Self-healing process in the as-prepared protein hydrogel. Figure 2. (a) CD spectrum of BSA solutions with and without heating. (b) FTIR spectrum of BSA solutions with and without heating. Figure 3. BSA size distributions. (a) BSA solution. (b) BSA solution