NMR补充说明.pptVIP

磁核和自旋量子数 磁核和自旋量子数 第1类：质子数和中子数均为偶数，质量数为偶数 磁核和自旋量子数 第2类：质子数和中子数均为奇数，质量数为偶数 磁核和自旋量子数 第3类：质子数和中子数其中一个为奇数，质量数为奇数 磁核和自旋量子数 磁核和自旋量子数 原子核的自旋角动量 原子核的总角动量来自于以下几个方面：质子的轨道角动量和自旋角动量，中子的轨道角动量和自旋角动量。 以上4个角动量耦合成原子核的总角动量。会有多个可能值。 乙醇的NMR谱图 乙醇的NMR谱图 Context When a trace amount of acid is added to the ethanol, the spectrum changes as shown in Fig. 1.4. The lack of multiplicity of the hydroxyl proton signal is due to rapid exchange of hydroxyl protons, which is catalyzed by acid. As a result of this exchange any one hydroxyl proton, during a certain interval of time, is attached to a number of different ethanol m