第4章化学反应速率复习资料.pptVIP

Temperature dependence of reaction rate k = Ae -Ea/RT A = frequency factor (pZ) Ea = activation energy (J) R = gas constant (8.314 J/mol·K) T = temperature (K) * * Linear form: ln k = -Ea/RT + ln A Y = mX + b Arrhenius 反映了速率常数和温度的关系 * * Ea is the activation energy A is called the frequency factor – an estimate of the number of reactive collisions in the system Reaction possesses a large activation energy ? small rate constant Slow reaction!! Measure k at several different temperatures * * Ea和Arrhenius 公式 R = 8.314 J/(K mole) T in Kelvin units!!! * * 由不同温度下反应速率常数，根据Arrhenius公式