水传递实例-2016.ppt

2.3 Electro-osmotic drag (EOD) in PEM by diffusion by electro-osmotic drag (EOD) Anode Cathode H2 O2 H2O excess O2 H2O excess H2 Electrical Circuit Electro-osmotic drag Water diffusion Dragging of water molecules by protons Membrane dehydration, especially at anode side, causing ohmic losses EOD coefficient, α (mol water/ mol proton) Anode Cathode H2 O2 H2O excess O2 H2O excess H2 Electrical Circuit Electro-osmotic drag Water diffusion For fuel cell operated with dry reactant feeds, maximum back-diffusion of water = Dry feed operation of fuel cells requires α 0.5 Scatter in EOD co