SnO2空心纳米结构的无模板合成讲述.ppt

Adv. Mater. 2006, 18, 2325–2329 Adv. Mater. 2006, 18, 2325–2329 Template-Free Synthesis of SnO2 Hollow Nanostructures Group 10 Wang He S(reporter) Chen You-Jun SWen Mei-Wang SFang Da-Ru SChen Wei S Department of Materials Science and Engineering, USTC References Formal method Templating routes Use removeable materials as templates to give desirable morphology Experimental TEM Precursor concentration Addictives The addition of urea or thiourea in the synthetic mixtures was found to be well dispersed with good monodispersity Pure SnO2 Temperature Synthetic parameter The precursor concentration Additives Temperature Concentration, the r value (EtOH vol% in the solvent of EtOH–H2O) or polarity of the mixed solvent well-defined hollow nanospheres can hardly be produced when r is lower than 30 %. Plausible mechanism Plausible mechanism Plausible mechanism Ostwald Ripening Growth of bigger particles (of monocrystal) at the expense of smaller ones Plausible mechanism Schematic illustration of SnO2 hollow structrue Cycling performance a) SnO2 hollow nanospheres in the current work; b) SnO2 hollow spheres from reference [3] c) pristine SnO2 nanoparticles from reference [4] Conclusion Method A simple one-step template-free method for the controlled synthesis of hollow or hollow core/shell-type SnO2 nanostructures. Application The as-prepared SnO2 hollow nanospheres exhibit superior lithium storage capacity and cycle performance when used as anode materials in lithium-ion batteries. Ostwald Ripening in nanowires growing Ostwald Ripening in nanowires growing * * Adv. Mater. 2006, 18, 2325–2329 Adv. Mater. 2006, 18, 2325–2329 Adv. Mater. 2006, 18, 2325–2329 Adv. Mater. 2006, 18, 2325–2329 [1] Adv. Mater., 12, 206-209(2000) [2] Adv. Mater., 18, 2325–2329(2006) (Key Ref) [3] Chem. Mater., 18, 1347(2006) [4] Power Sources, 144, 220(2005) [5] Nature, 440, 69-71(2006) Z. Zhong,e