铝系钢坯表面高温防氧化涂层的研究论文.docVIP

河北理工大学 本科生毕业论文 题 目： 铝系钢坯表面高温防氧化涂层的研究 英文题目： Surface oxidati on defending coatings on steel billet at high temperature 学 院： 材料学院 专 业： 材料化学 班 级： 姓 名： 学 号： 指导教师： 2010年 6 月 10 日 摘 要 高温氧化是钢材热加工中质量损失的主要原因之一。这种氧化现象还会给钢材的制造过程带来许多不利的影响，如产品收得率低下、单位钢产能耗增加、生产成本提高，严重时还会影响生产过程中的正常工序操作，影响产品的最终质量甚至会造成事故。因而，有必要采取措施，防止或降低因高温氧化而产生的损失。涂层保护技术是解决这一问题的有效方法之一。比起真空保护技术和惰性气体保护技术，它具有工艺简单、保护效果显著、成本低等特点。通过综合分析相关文献报道，我们采取了惰性熔膜保护机理，研制了一种高温抗氧化效果较好，冷却时具有自剥落性能的氧化物陶瓷涂料。我们以热力学稳定性、表面张力以及线膨胀系数为选材依据，对原料的进行了反复地筛选，然后用实验优化配方。通过此思路不断改善涂料的性能，得出了最佳实验配方。 关键词：高温氧化，涂层，钢材，热力学。 Abstract High-temperature oxidation is one of the main ceauses of steel loss during heat treatment proeess . It brings many disadvantageous effeets for manufacturing ，such as low production efficiency， high energy-consumption and thus high production cost . The steel oxide can even affect normal manipulation in routine manufacture and depress final product quality. Therefore ,it is neeessary to avoid or reduce high-temperature oxidation of steel . protcetive coating is one of the most effective methods to solve this problem.Compared to the proceeding vacuum furnace technique or inert-gases protcetion technique of heat treatment coating technique has more advantages. It is provided with a simple preparative technics a better protective ability and lower unit cost. Based on previous reports and laboratory tests ，we successfully developed a kind of oxide ceramic coating ， adopting inert shield protective mechanism. This coating can effectively resist oxidation and can scale off inartificially from steel samples.In choosing raw materials，we took into account thermodynamics stability，surface tension，and distensibility. Then，we used chiastic experimentations to optimize direction of these materials，and finally established the best coating prescription through high-temperature performance