《柯坪剖面中上奥陶统烃源岩的催化加氢裂解产物特征及其地质意义.doc

柯坪剖面中上奥陶统烃源岩的催化加氢裂解产物特征及其地质意义 王庆涛1,2, 江林香1,2, 刘奇宝3, 曾 建1,2,卢 鸿1*, 刘金钟1, 彭平安1 (1.中国科学院广州地球化学研究所 有机地球化学国家重点实验室, 广东 广州 510640; 2.中国科学院 研究生院, 北京 100049; 3.山东黄金集团 昌邑矿业有限公司, 山东 潍坊 261300) 摘 要: 柯坪地区中上奥陶统萨尔干组和印干组页岩是塔里木盆地两套重要烃源岩，前人研究结果表明其游离态生物标志化合物含量极低，给精细的油源对比研究带来困难，因而本文采用催化加氢裂解的方法加以研究。相比常规索式抽提，少量干酪根的氢解反应可以获取足量准确的生物标志化合物信息，这主要跟氢解反应中高温供能、氢气保护、催化剂催化以及干酪根网格对其内部小分子的保护有关。高成熟演化和二叠纪岩浆热液活动的破坏作用，不是萨尔干组和印干组页岩中游离态生物标志化合物含量少的主要原因。柯坪地区中上奥陶统属较特殊的台缘斜坡、半闭塞-闭塞海湾沉积或深水陆棚-盆地沉积，在此特定沉积环境下发育的疑源类及其他中、低等生物类等母质输入，是造成游离态生物标志化合物含量极低的主要原因。 关键词: 中上奥陶统; 烃源岩; 催化加氢裂解; 萨尔干页岩; 印干页岩; 柯坪 中图分类号: P593 文献标识码: A 文章编号: 0379-1726(2012)05-0000-00 Catalytic hydropyrolysis for kerogens of middle and upper Ordovician source rocks in Keping Section, Tarim Basin, Northwestern China WANG Qing-tao1,2, JIANG Lin-xiang1,2, LIU Qi-bao3, ZENG Jian1,2, LU Hong1*, LIU Jin-zhong1 and PENG Ping-an1 1. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, CAS, Guangzhou 510640, China; 2. Graduate University of Chinese Academic of Sciences, Beijing 100049, China; 3. Changyi Mining Co., Ltd, Shandong Gold Group, Weifang 261300, China Abstract: Salgan and Yingan Shales in Keping area, the source rocks of middle and upper Ordovician in Tarim Basin, northwestern China, were characterized by the very low quantities of free biomarkers in the traditional Soxhlet extracts, and general steranes and hopanes can not be detected even in the SIM mode, which makes it difficult to find out the usual oil and source rock correlation. Thus, catalytic hydropyrolysis for the kerogens of these source rocks was conducted in order to explore more geochemical information. The results illustrated that little kerogen could display enough and complete biomarker information, which is contributed by high energy at high temperature, protection from H2 and catalysis from MoS2, as well as protection supplied by kerogen grid structure. High maturity and magmatic hydrothermal in?uence were not responsible for the lo