清华材料科学基础课件(英文)skja09.pptVIP

材料科学基础 材料科学基础Fundamental of Materials §3.4 Some Rules Governing the Ionic Compounds Pauling’s three rules governing the structure of ionic compounds. 1. Anion Coordination polyhedron rule Each cation is surrounded by an anion polyhedron, the distance between anion and cation is ro＝r+＋r-, while the CN depends on r+/r-. ro＞r+＋r－ 2. Valence rule There is a definite relation between valence and CN. Let S be the strength of electrostatic bonding between a pair of anion and cation §3.5 Crystal Structure of Ceramic Materials AB