高一化学必修1 计算 ppt.pptVIP

* * 一.计算P5 1. CaCO3 2HCl 1 2 534mg×10-3 100g/mol X X =10.68×10-3mol Mg(OH)2 2HCl 1 2 180mg×10-3 58g/mol y y =6.21×10-3mol C= n v V= n c =0.169L=169mL = 10.68×10-3mol+ 6.21×10-3mol 1mol/L ×10 2(1) n= V Vm = 4.48L 22.4L/mol =0.2mol (2) 2Cl2~~~~~Ca(ClO)2 1 0.2mol x X=0.1mol m[Ca(ClO)2]=0.1mol×143g/mol =14.3g 2Cl2+2Ca(OH)2===CaCl2+Ca(ClO)2+2H2O 3. CaCO3+2HCl==CaCl2+CO2↑+H2O 1 1 1 X y 1.12L 22.4L/mol =0.5mol X=0.05mol y=0.05mol (1)w(CaCO3) = 0.05mol×100g/mol 8.0g =62.5% ×100% (2)C(CaCl2)= 0.05mol 0.05L =1mol/L 4. Na2SO4+BaCl2==BaSO4↓+2NaCl Na2CO3+BaCl2==BaCO3↓+2NaCl 1 1 x 4.66g 233g/mol =0.02mol X=0.02mol 1 1 y (14.51-4.66)g 197g/mol =0.05mol y=0.02mol (1)C(Na2SO4)= 0.02mol 100×10-3L =0.2mol/L C(Na2CO3)= 0.05mol 100×10-3L =0.5mol/L (2)BaCO3+2HNO3=Ba(NO3)2+CO2↑+H2O 1 1 0.05mol z Z=0.05mol V=0.05mol×22.4L/mol =1.12L 5. (1)m(NaOH)=0.20mol/L×1L×40g/mol= 8g (2)Mg2++2OH-=Mg(OH)2 1 2 Mg2+= 200mL×0.2mol/L 100mL×2 =0.2mol/L (3)MgCl2(熔融）=== 电解 Mg+Cl2↑ 1 1 0.2mol/L×100×10-3L X X=0.02mol v(Cl2)=0.02mol×22.4L/mol= 0.448L 6. NaCl+AgNO3==AgCl↓+NaNO3 1 1 X 2.87g 143.5g/mol =0.02mol X=0.02mol (1)w(NaCl) = 0.02mol×58.5g/mol 5.0g ×100% =23.4% 20%,不符合 （2）C(NaCl)= 0.02mol 50×10-3L =0.4mol/L *