小分子有机电致发光器件OLED的研究及应用发展.docxVIP

小分子有机电致发光器件的研究及应用发展摘 要 有机电致发光器件(OLED) 是在电场作用下，以有机材料为活性发光层的器件。OLED具有效率高、亮度高、驱动电压低、响应速度快以及能实现大面积光电显示等优点，因其在平板显示和高效照明领域具有极大的应用前景而引起广泛关注。本文综述了小分子OLED 的各种器件结构，着重介绍了每种器件的结构及相关工作原理，并对其性能进行讨论。包括:单层、双层、三层及多层器件，白光器件。继而介绍近年来国内外OLED的研究及商业应用状况。最后提出了小分子OLED在技术方面存在的主要问题和挑战，并简单介绍了其未来的发展趋势。关键词 有机电致发光器件(OLEDs) 器件结构 工作机制 产业现状Research of Devices and Development of Applicationsfor Small Molecular Organic Light-emitting DiodesAbstract Organic light-emitting diodes (OLEDs) are electrical driven devices which contain organic materials as emitting media. Because of OLEDs have excellent properties of high light -emitting efficiency, high brightness, low driving voltage, fast response, potential for fabrication of large-area full-color flat panel display and so on, the OLEDs have been extensively studied due to their possible applications for flat panel color displays and illumination source. In this paper，we review the progress in OLED research of devices，as well as OLED applications. Firstly，devices with different structures，such as single-，double-，triple-and multilayer devices，as well as white OLED device are discussed. Secondly, we introduce the research and commercial application condition for OLEDs at home and abroad in recent years. Finally，the current challenges for applications are highlighted，and the focus of future research and development are proposed.Key words organic light emitting diode (OLEDs); device structure; working principle; industry status quoContents1 Introduction2 Basic structure and operating principle in OLEDs2. 1 Single-layer OLED device2. 2 Double-layer OLED device2. 3 Triple-layer OLED device2. 4 Multi-layer OLED device2. 5 White OLED device3 The applications，prospects and challenges inOLEDs3. 1 Applications3. 2 Prospects3. 3 Challenges1 引言电致发光(EL) 是指在一定的电场下，一些有光电性质的材料被相应的电能激发，从激发态回到基态时产生的发光现象。1963 年，PoPe[1,2]等人以电解质溶液为电极，在蒽单晶的两侧加400 V 直流电压时，观察到了蒽的蓝色EL。随后，Helfrich等人对蒽单晶的EL作了进一步研究。由于电解质溶液电极制作工艺复杂，1969年，Dresener等人在有机EL器件中引入了固体电极。1970 年，Williams 和Schadt[3]利用蒽单晶首