6-nmr-organomet.pptVIP

Multinuclear Approach Proton NMR spectra: 3 groups of peaks integrating for 12:4:1 Resonances due to Methyl and CH2 have coupling with 31P And also shows satellites due to mercury coupling (199Hg 16.8%) While third resonance is broad In 31P, there is a single signal: Symmetrical compound: that has Mercury satellites In 199Hg NMR (with proton decoupling): quintet demonstrate the presence of 4 Phosphorus Index Heteronuclear NOE NOE enhancement can give useful gain in signal-to-noise It is most efficient when the heteronuclei is bound to proton NOEMAX = 1 + gH/2gX For nuclei having negati