ppt课件-质量光谱 la salle 大学（ mass spectrometry- la salle university）.pptVIP

McLafferty Rearrangements in Alkyl Benzenes Benzamide 2-Octanone 2-Octanone Decanoic Acid p-Chloroacetophenone Methyl Octanoate 2,4-Dimethoxyacetophenone Cyclohexanone High Resolution Mass Spectrometry Determination of Molecular Formula Isotope Ratios Can Help to Determine Molecular Formula Relative intensities (%) MF MW M M+1 M+2 CO 28.0 100 1.12 0.2 N2 28.0 100 0.76 ---- C2H4 28.0 100 2.23 0.01 Comparisons of Molecular Weights and Precise Masses MF MW exact mass C3H8O 60.1 60.05754 C2H8N2 60.1 60.06884 C2H4O2 60.1 60.02112 CH4N2O 60.1 60.03242