LiOH-LiNO3低共熔混合锂盐体系合成LiNi13Co13Mn13O2..docVIP

修改稿 LiOH-LiNO3低共熔混合锂盐体系合成LiNi1/3Co1/3Mn1/3O2常照荣, 陈中军，吴锋, 汤宏伟, 朱志红 (1. 河南师范大学化学与环境科学学院，河南 新乡453007 ；2. 北京理工大学化工与环境工程学院, 北京100080) 摘 要: 利用低共熔组成的0.38LiOH·H2O -0.62LiNO3混合锂盐体系，与钴、镍、锰的氢氧化物在低温下自混合, 无需前期研磨和后续洗涤,直接制备出锂离子正极材料LiNi1/3Co1/3Mn1/3O2。X射线衍射分析表明合成的Li(Ni1/3Co1/3Mn1/3)O2结晶度高，具有规整的层状α-NaFeO2结构扫描电镜显示产物颗粒均匀，振实密度高达2. g·cm-3。XPS分析合成的样品中Ni、 Co、Mn的价态分别是2+、3+、 4+。充放电测试表明材料具有良好的电性能，首次放电为160 mhA·g-1,循环50次后,材料的电性能没有明显的衰减。关键词：低共熔盐；正极材料; XPS;LiNi1/3Co1/3Mn1/3O2 中图分类号：646; O614; TM 912.9 Synthesis of LiNi1/3Co1/3Mn1/3O2 Cathode Material by Eutectic Molten Salt LiOH-LiNO3 CHANG Zhao-Rong 1,2 CHEN Zhong-Jun1 WU Feng2， TANG Hong-Wei1 ZHU Zhi-Hong1 (1.College of Chemistry and Environmental Science, Henan Normal University,Xinxiang 453007，Henan Province, P. R. China 2.College of Chemical Engineering and Environmental,Beijing Institute of Technology, Beijing 100080, P. R. China) Abstract: The powder of Li(Ni1/3Co1/3Mn1/3)O2 has been prepared directly without artificial grinding and washing by a eutectic molten-salt mixture(0.62LiNO3–0.38LiOH·H2O)method .According to this method ,the eutectic molten-salt mixture were self-mixed with precursor thoroughly at low temperature?,and then sintered at a certain temperature. The tap-density of the powder obtained was 2.87?g·cm-3, The well-layered α-NaFeO2structure and regular morphology were confirmed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). XPS studies show that the predominant oxidation states of Ni, Co and Mn in the compound are 2+, 3+ and 4+, respectively. Cathodic behaviour was examined by charge-discharge cycling, The synthesized powder showed a reversible capacity of 160 mAh·g-1 at a specific current of 0.2 C in the rang 3.0～4.3 V up to 50 cycles with no noticeable capacity-fading . Key Words: Eutectic molten salt; Cathode material; XPS; Li(Ni1/3Co1/3Mn1/3)O2以 LiNi1/3Co1/3Mn1/3O2为代表的三元系具有容量高、循环性能好、热稳定性高以及价格较低等优点，被认为是替代LiCoO2 的最有前景的锂离子正极材料，成为近年来的研究热点[1-7]。Li(Ni1/3Co1/3Mn1/3)O2的合成通常采用高温固相法、溶胶凝胶法和共沉淀法等[