CN101327945A 纳米氧化铜[精].docVIP

Cupric oxide nanoparticle having superior water dispersibility and preparation thereof 氧化铜纳米粒子CN 101327945 A 摘要 The invention discloses copper oxide nano-particles with well water dispersibility comprising: coating hydrophilic polymer materials with a thickness of 1-10 nm outside the surface of copper oxide nano-particles, wherein the hydrophilic polymer materials are selected from one of low polyacrylic acid, low potassium polyacrylate, low calcium polyacrylate, low zinc polyacrylate, low polyethyleneglycol or low polyvinyl acetate, the diameter of the copper oxide nano-particles is 60-140 nm. The copper oxide nano-particles with well water dispersibility of the invention are prepared by forming a hydrophilic oligomer single film on the surface of the copper oxide particles through a simple free radical polymerization method. The water dispersive solution of copper oxide nano-particles with well dispersiblity is directly prepared without further purify. 权利要求(2)??翻译自中文 1、一种具有良好水分散性的氧化铜纳米粒子，其特征在于：所述具有良好水分散性的氧化铜纳米粒子是在氧化铜纳米粒子的表面包覆有1～10nm厚的亲水聚合物材料； 所述亲水聚合物材料是低聚丙烯酸、低聚丙烯酸钠、低聚丙烯酸钾、低聚丙烯酸钙、低聚丙烯酸锌、低聚乙二醇或者低聚醋酸乙烯之一； 所述氧化铜纳米粒子的直径为60～140nm。 1, having a good water dispersibility of the copper oxide nanoparticles, characterized in that: said water-dispersible with good copper oxide nanoparticles in the surface of copper oxide nanoparticles coated with a thickness of 1 ~ 10nm hydrophilic polymeric object material; said hydrophilic polymeric material is oligomeric acrylic acid, low sodium polyacrylate, polypropylene, low potassium, low calcium polypropylene, polypropylene, low zinc, oligo ethylene glycol or oligomers of vinyl acetate; wherein CuO nanoparticles have a diameter of 60 ~ 140nm. 2、 一种制备如权利要求1所述的具有良好水分散性的氧化铜纳米粒子的方法，其特征在于包括有下列步骤：第一步：配置二价铜离子溶液，所述二价铜离子溶液的浓度为1?3mo〃Z; 所述二价铜离子溶液可以是硝酸铜、硫酸铜、氯化铜；第二步：将第一步配制的二价铜离子溶液置于可加热的超声清洗器中，加热至50?100。 2, A process as claimed in claim 1 having a good water dispersibility of the copper oxide nanoparticles, characterized in that it comprises the f