ppt课件-iontransportanalysis.pptVIP

Neah Power Systems, Inc. – Ionic Conductivity – C. Nelson – Jan 27, 2005 – Company Confidential Regarding Ion Transport in Electrolyte Solutions Craig E. Nelson - Consultant Engineer Charge Mobility – Absolute – any Kind of Force From Bockris and Reddy Vol 1 pages 370 - 371 Absolute Mobility = ua = drift velocity / force Let z = # charges per particle e = charge of an electron = 4.8 * 10 ^ -10 {statcoulomb} X = electric field {volts/cm} 1/300 = electrostatic unit conversion factor Force = F = z*e*X*(1/300) {dynes} 1 dyn = 10^ -5 Newton Force = F = z*e*X*(1/300)*(10^ -5) {Newtons} Example: X = .05 volt/cm Vdrift = 2*10^ -5 cm/sec Force = 8 * 10 ^ -14 {dynes} Force = 8 * 10 ^ -19 {Newtons} Uabs = 2.5*10^ 8 { cm / (sec * dyne ) } Uabs = 2.5*10^ 13 { cm / (sec * Newtons ) } Charge Mobility – Conventional – Electric Force Only From Bockris and Reddy Vol 1 pages 370 -371 Conventional Mobility = Uc = Vd / X = (1/300) * z * e * Uabs {cm^2 / (volt * sec) Absolute Mobility = Uabs = Vd / F = (300 * Uc) / (z*e) {cm / (sec*dyne) Example: X = .05 volt/cm Vdrift = 2*10^ -5 cm/sec Uconv = 4*10^ -4 { cm^2 / (volt*sec ) } Ion Conductivity – Electric Force Only From Bockris and Reddy Vol 1 pages 373 Particle Flux Density = J = concentration * velocity { moles/(cm^2 * sec } Current Density = I = z* F * Conc * Vel { amperes / cm^2 } F = 9.48 * 10 ^ 4 { coulomb / mole } Conc = {moles / cm^2 } Note : Conc = {moles / cm^2 } = (1/1000) * Conc {moles/liter} Conductivity = sigma = I / X { siemens / cm } Sigma = z * F * Conc * Uconv Absolute Mobility and Diffusion Coefficient – Einstein Relation From Bockris and Reddy Vol 1 pages 374 Particle Flux Density = Jd = concentration * velocity = - D* dC/dx { moles/(cm^2 * sec } Vdrift = Uabs * Force { cm/sec } Current Density = I = z*F*Conc* Vd { amps / cm^2 } Conduction Flux Density = Jc = I / (z*F) = Conc * Vd = {moles / ( cm^2 * sec )} Jc = Conc * Uab