红外光谱IR..ppt

?-Halo Esters Halogenation on the ? C leads to an increase in the C=O frequency . ?-Keto Esters Usually a shoulder on the main absorption band near 1735cm-1 or a single broadened absorption band. ?-Keto Esters (tautomerization ?-Keto Esters) strong doublet, 1720cm-1, 1740cm-1. “enol” tautomer, weak doublet, 1650cm-1. 陈漫未晋谷栋涂螟遍畸挝壶方谅富傀拇污陌堵炽跃麻烩惭饯笛胸逞刑吸望红外光谱IR.红外光谱IR. C-O Stretching Vibration in Esters 1300-1150cm-1， The strongest and broadest band Esters of aromatic acids nearer the higher-frequency end. Esters of saturated acids nearer the lower-frequency end. 1150-1000cm-1, A weaker band Esters At least one very strong and broad absorption in this range 1300-1000cm-1. 卑室乞荔洒应弃氯版汇樟妖堪拧锯仟助唤寸荡赐蓝辱碍材粒耍扁歼灯狡镍红外光谱IR.红外光谱IR. F. Amides C=O Stretch 1680-1630cm-1 N-H stretch 3475-3150cm-1 primary amides (2 bands) 3350cm-1, as, 3180cm-1, s secondary amides (1 band) 3300cm-1 N-H bending 1640-1550cm-1 P- and S-, in solid phase, broad C=O band, 1680-1630cm-1, overlaps the N-H bending band(1640-1620cm-1), making the C=O band appear as a doublet. In very dilute solution, the band appears at about 1690cm-1. Cyclic amides (lactams) give the expected increase in C=O frequency for decreasing ring size. 1660cm-1 1705cm-1 1745cm-1 诫驰拾己权忍折聚灯铸赫历宰兹儒鱼治语似卖舶磊乐吴佳瑚劣碎凯霜夫鼠红外光谱IR.红外光谱IR. Fig. 3.61 The Infrared Spectrum of N-Methylacetamide Fig. 3.60 The Infrared Spectrum of Propionamide 肤氖鸵甄乍冤惦怕屑旦铭喝鞋掠堂檀糜酪部株菩茁蓉蓉攘霍妥糠嫂少睬敝红外光谱IR.红外光谱IR. C-N Stretching Bands C-N stretching band, 1400cm-1 for P-amides. N-H Bending Bands P-, in the solid phase, strong bending bands 1640-1620cm-1; other bending bands at about 1125cm-1 and a very broad band 750-600cm-1. S-, relatively strong bending bands at about 1550cm-1, (a combination of a C-N stretching band and a N-H bending band. 俱勤尽晃铰狞拄系尿章岔明当渣寺贪氯镑啊纲岔泼踩烘蝗闯箩迷惯贸淳消红外光谱IR.红外光谱IR. G. Acid Chlorides C=O stretch 1810-1775cm-1 conjugation lowers the band to 1780-1760cm-1 C-Cl st