WORK REPORT幻灯片.pptVIP

WORK REPORT Gao Peng 2011.12.19 Graphene-Based Nanomaterialsand their Applications in Energy-Related Areas 1.OPV research advances 2.Li-ion Batteries and Supercapacitors Graphene as the Transparent Electrode Material ITO used as the hole collecting electrode CNTs transparent electrode of OPV cells：PCE 2.5% rGO films as transparent electrode ：P3HT as electron donor ；PCBM as acceptor (1).spin-coating GO films(25nm) (2).hydrazine vapor reduction ,then anneal under inert conditions Adv. Mater. 2011, 23, 5342–5358 (a)Device structure of OPV (b) Optical transmittance spectra of GO(40nm) and rGO(25nm) (c)Photograph of rGO/PET.(d)Sheet resistance and transmittance of rGOfilms (e)Schematic representation of the device structure (f)Current density-Volltage(J-V)curves of the device 1 after applying (ⅰ)400(ⅱ)800(ⅲ)1200 cycles of bending 2010,ACS (a)Energy diagram of the fabricated device (b)-(e) Current voltage characteristics of the photovoltaic devices based on Gr-filmes in dark and under illumination ,where(b) is from pristine Gr-film,(c)Gr-film treated by UV leight,(d) Gr-film modified by PBASE.(e)ITO anode for comparison. 2009,AIP Graphene as an Acceptor Material In OPV devices,the separation of the photoexicted clectron-hole pairs can be achieved by creating a heterojunction with the acceptor material Two types of heterojunctions have been widely used:bilayer or planar heterojunction structure and an intermixed bulk heterojunction(BHJ) structure The idealized chemical structures of garaphene and P3OT Schematic of the device (c)Energy level diagram of P3OT andSPFGr (d)Schematic representation of the reaction of phenylisocyanate with GO to form SPFGr. 2008,Wiley-VCH Schematic of the devics with P3HT/f-MWCNT-SPFGr as the ac