阴离子型菱形网状的手性多孔铟金属有机框架：合成、结构和氮气吸附要点.doc

01 July 2011 doi:10.1039/C1CE05110E UNIVERSITYon |  CrystEngComm View Online Dynamic Article LinksC Cite this: CrystEngComm, 2011, 13, 4005 /crystengcomm PAPER A porous chiral In-MOF with anionic-type diamond network: synthesis, structure and nitrogen gas adsorption? Liping Wang,a Tianyou Song,a Liangliang Huang,a Jianing Xu,*b Chao Li,a Caixia Ji,a Liang Shana and Li Wang*a Received 21st January 2011, Accepted 18th March 2011 DOI: 10.1039/c1ce05110e A novel porous chiral In-MOF InH(D-C10H14O4)2 (1) with a left-handed helical channel assembled from D-(+)-camphoric acid (D-H2Cam), has been prepared under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the tetragonal space group 3 P43212 (no. 96) with parameters: a ? 13.8954 A, b ? 13.8954 A, c ? 17.7870 A, V ? 3434.4(7) A , Z ? 4. The framework feature of compound 1 is characteristic of four-connected anionic-type diamond net with left-handed chiral channel. Moreover, compound 1 exhibits high surface area.  Downloaded by NANJING Published on 13 April 2011 on Introduction The design and synthesis of porous metal–organic frameworks (MOFs) with characteristic structural chirality are topics of current interest and of great challenge in materials science,1,2 not only due to their intriguing structures, but also owing to their potential applications as functional materials for enantioselective catalysis and separation, non-linear optics, ferroelectrics and magnetism.3–7 Recently, the synthesis of chiral low-connectivity (3- or 4-connected) MOFs attracts special attention on accounts of their appealing architectures and high surface areas.8 To our knowledge, compared with tremendous success in the synthesis of low-connectivity framework materials in the past decades, 3D chiral low-connectivity MOFs are still rare. More recently, In-MOFs continue to receive much attention due to their flexible coordination char