(二氧化碳共聚物的扩链改性.docVIP

二氧化碳共聚物的扩链改性 摘 要 聚碳酸亚丙酯（Poly propylene carbonate, 简称PPC），又名聚甲基乙撑碳酸酯，是以二氧化碳（CO2）和环氧丙烷（PO）为原料合成的一种热塑性可生物降解的环保型材料。与其他聚酯相比，PPC 价格低廉，可以完全降解，加上其优异的气体阻隔性和生物相容性，PPC广泛应用于肉制品保鲜膜、可降解泡沫材料、食品包装材料等。但 PPC 的玻璃化转变温度较低，材质柔软。端羟基的存在使得 PPC 容易发生“解拉链式”降解，影响其加工和使用性能。因此，对 PPC 进行物理或化学改性，通过扩链反应提高其分子量或降低熔融指数，提高其力学性能和热性能，具有较大的实际意义。 本文主要研究PPC的扩链改性，采用熔融聚合的方法，将二氧化碳共聚物PPC、甲苯二异氰酸酯（TDI）和扩链剂1、4-丁二醇（BDO）混合进行扩链反应。通过特性黏度法测定共混物的分子量，利用红外测定共混物的结构，利用热分析仪研究共混物的热性能，利用万能拉力机测定其力学性能。最终得到具备良好力学性能和耐热性能的高分子量的产品。 关键词：聚碳酸亚丙酯；PPC；甲苯二异氰酸酯；TDI；1、4-丁二醇；BDO；玻璃化转变温度；端羟基；熔融指数；力学性能；热性能 Chain Extension Modification of Carbon Dioxide Copolymer Abstract Poly propylene carbonate(PPC for short), is also called poly methyl ethylene carbonate. PPC is a kind of thermoplastic and biodegradable environment friendly materials which is composed of carbon dioxide(CO2) and propylene oxide(PO). Compared with the other polyesters, PPC is much cheaper and it can be completely degraded. Besides, PPC has excellent gas barrier properties and biocompatibilities. Therefore, PPC is widely used in meat preservative film, biodegradable foams, food packaging materials etc. But the glass transition temperature of PPC is low, which makes it very soft. The exist of hydroxyl terminated makes it easy for PPC to degrade with the form of “unravelleding chain”which affects its processing and functional performance. Consequently, it has great practical significance on the physical or chemical modification of PPC, improving the molecular chain or reducing the fusion index through the chain extension reaction. This article is focus on the research of the chain extension of PPC. We will mix carbon dioxide copolymer(PPC), toluene diisocyanate(TDI) and 1, 4- butanediol(BDO) to carry out chain extension reaction by using the method of melt polymerization, determining the molecular weight of blends with gel permeation chromatography(GPC) and the structure with infrared spectrometry and nuclear magnetic resonance. Thermal properties of blend will be stud