X射线荧光仪在水泥生产过程中的一套监控方法(应晓浒,布鲁克)讲解.ppt

DXC 2008 * S-Speciation: Sulfide-Sulfate2. Overlap Method: Sulfate calibration Calibration Curve; 30s/0.3%; RSD=0.30% DXC 2008 * 硫化物-硫酸根 3、谱线强度比 方法 the third method to determine total sulfur and the sulfate amount is to use the K?- line (S KB1-HS) for total sulfur determination the ratio K?-line/K?-line(S KA1-HS/ S KB1-HS) for the determination of the sulfate amount DXC 2008 * S-Speciation: Sulfide-SulfateS KA1 coarse collimator ( S total?) DXC 2008 * S-Speciation: Sulfide-SulfateS KB1 coarse collimator ( S total) DXC 2008 * S-Speciation: Sulfide-Sulfate3. Ratio Method: Sulfur calibration Calibration Curve; 100s/0.3%; RSD=0.97% DXC 2008 * S-Speciation: Sulfide-Sulfate3. Ratio Method: Sulfate amount Calibration Curve; 30s/0.3% + 100s/0.3%; RSD=0.0014 DXC 2008 * 硫化物-硫酸根：水泥标准样品的结果比较1. 伴线方法 DXC 2008 * 硫化物-硫酸根：水泥标准样品的结果比较2. 谱线重叠方法 DXC 2008 * 硫化物-硫酸根：水泥标准样品的结果比较3. 强度比方法 DXC 2008 * 硫化物-硫酸根：三种方法的比较 DXC 2008 * Title picture can be exchanged in the masterslide. * * * * * When a high energy photon collides with matter electrons can be ejected from the atoms. Electrons may be ejected (i.e. removed to infinity as far as that atom is involved) from the inner energy shells, thus creating positive holes or vacancies. This electron leaves the shell with an energy equal to the photon energy less the K-shell electron-binding energy. Due to re-arrangement the positive holes may be filled by electrons from outer orbitals. Each time an electron is transferred the atom moves to a less energetic state and radiation is emitted at a wavelength corresponding to the difference in the energy between the initial and final states of the transferred electron. The energy in this way created is being released as a K-, L- or -M-Quant. The name depends on the energy level in which the hole is being filled up. For example, if a K electron is ejected and the hole is filled up by an L-electron the energy released will be equivalent to EK-EL.also called a Ka line. The L-vacancy may the