第七-八章-煤有机质的化学结构及方法例析.ppt

Complex intermolecular actions occur between two phases in coal. Coal organic matters are rich in aromatic ring structures (and always aliphatic rings as well). Coal macromolecules take these rings as structural units, and are polymerized by linkages of ―(CH2)n―、―O― and ―S― . The size and condensation degree of aromatic ring unit in coal increase with metamorphic grade of coal, while the number of linkages reduce. The small molecular phase of coal is also quite a complex organic system, and aliphatic, alicyclic and aromatic hydrocarbons as well as heteroaromatics and other polar compounds ar