PTFE基复合材料的制备及其摩擦磨损性能的研究.docVIP

哈尔滨工业大学2009届本科优秀毕业设计（论文）选集 PAGE 173 - PTFE基复合材料的制备及其摩擦磨损性能的研究 机电工程学院：王志斌 指导教师：宋宝玉 摘 要：本文研究了不同纳米材料与MoS2混合填充的PTFE的摩擦磨损性能。用机械混合法分散，冷压烧结工艺制备PTFE基复合材料。用MM-200型摩擦磨损试验机研究纳米铜(Cu)、纳米氮化硅(Si3N4)、纳米氧化锌(ZnO)和纳米碳化硅(SiC)与二硫化钼(MoS2)混合填充PTFE的摩擦磨损性能，用金相显微镜分析了磨损机理。研究结果表明：PTFE基复合材料的磨损量随着施加载荷的增大而增加；纳米材料的加入使PTFE的磨损量明显减小；纳米SiC减小了PTFE的摩擦系数，而纳米Cu、纳米Si3N4、纳米ZnO则增大了PTFE的摩擦系数。在本试验条件下，为使复合材料能获得最佳的摩擦磨损性能,每种纳米材料的最佳填充含量：纳米Cu为10%、纳米Si3N4为9%、纳米ZnO为7%、纳米SiC为7%。 关键词：PTFE基复合材料；纳米Cu；纳米Si3N4；纳米ZnO；纳米SiC；摩擦磨损机理 Abstract：This issue has discussed the friction and wear properties of PTFE which is filled with different kinds of nano-materials and MoS2. PTFE-based composite have obtained by mechanical mixture and compression molding..The friction and wear properties of PTFE which is filled with nano-Cu,nano-Si3N4,nano-ZnO,nano-SiC and MoS2 has discussed with MM-200 wear and friction tester.,while the friction and wear mechanism is analysed with metallographic microscope The experiment gives the following results: the wear mass loss of PTFE composite increase with the increase of the load; the addition of nano-materials decrease the wear mass loss of PTFE; the addition of nano-SiC decreases the friction coefficient of PTFE,while the addition of nano-Cu,nano- Si3N4 and nano-ZnO increases the friction coefficient of PTFE. During the experimental conditions, in order to get the best friction and wear properties of composite materials,the best filled content of each nano- materials is as follows: nano-Cu is 10%, nano- Si3N4 is 9%, nano-ZnO is 7%,while nano-SiC is 7%. Key words：PTFE-based composite;nano-Cu;nano-Si3N4;nano-ZnO;nano-SiC; friction and wear mechanism 引 言 聚四氟乙烯（PTFE）具有很好的耐高低温性能，在大气和真空中都具有良好的润滑性能，而且这种材料在大气环境中的耐腐蚀能力相当强，但PTFE的机械强度差，回弹性差，硬度较低，耐磨性较差。通过在PTFE中添加不同的改性材料，采取不同配比，用合适的工艺制备出PTFE基复合材料。 纳米材料是近年来发展起来的具有优异性能的新材料，具有独特的小尺寸效应、表面效应等许多常规材料不可能具有的特性。用纳米材料改性的聚合物不仅能全面改善聚合物的综合性能，而且还能赋予其特殊的性能，为聚合物改性提供了新途径。[1] 本文主要研究了纳米Cu、纳米ZnO、纳米Si3N4、纳米SiC与MoS2混合填充的PTFE的摩擦磨损性能。主要进行了PTFE基复合材料的制备，并进行摩擦磨损试验,通过试验比较不同配比、载荷等条件下对相同