指导教授：王振乾教授研究生：符昌中.pptVIP

指導教授:王振乾教授 研究生:符昌中 聚氨酯(Polyurethane,PU)包含異氰酸鹽與羥基化合物，在工程材料上應用廣泛，且幾乎每天都有新的用途出現。 由於異氰酸鹽和羥基化合物反應性高，因此產生雙組成(Two package)的構想，而雙組成聚氨酯在設備及成本上需要較多的花費。 Introduction 封閉型聚氨酯，是一個經由熱硬化方式所獲得的聚氨酯，此可降低異氰酸鹽對水氣的敏感性，及毒性。 本研究是探討不同結構的異氰酸鹽在封閉、解封閉和硬化反應中的熱力學和動力學反應。 Introduction N-methylaniline (NMA) (Lancaster) 4,4-Methylenebis(phenylisocyanate) (MDI) (Lancaster) Toluene 2,4-diisocyanate(TDI) (Aldrich) 1,6-Diisocyanatohexane (HMDI) (Fluka) Isophorone diisocyanate (IPDI) (Aldrich) Phenyl isocyanate(Aldrich) Materials Polytetrahydrofuran (PTHF,Mn =2000) (Aldrich) Polypropylene glycol (PPG, Mn = 2000)(Aldrich) Poly(e-caprolactone diol) (PCL, Mn = 2000) (Aldrich) Dibutyl amine (Fluka) were used as received. Materials Hydroxyl-terminated polybutadiene (HTPB, Mn = 2500) obtained from Vikram Sarabhai Space Centre, was used after drying for 2 h at 80℃ under vacuum. Toluene (Merck), methanol (Merck) and chloroform (Merck) were purified according to standard procedures. Materials NMA/CH2Cl Diisocyanate/CH2Cl N2 The reaction was monitored using FTIR, and the procedure was stopped when complete disappearance of absorption due to -NCO group in the FTIR spectrum. Petroleum ether 60-80 ℃ Filtered,dried in air and recrystallized from toluene. Synthesis of adduct Synthesis N-methylaniline-blocked polyisocyanates (5-8) based on poly(tetrahydrofuran) (Terathane-2000) were prepared according to a procedure described in our pervious report. Synthesis of prepolymer MDI TDI IPDI HMDI Adduct 1 2 3 4 Prepolymer 5 6 7 8 Synthesis In the case of aromatic isocyanates, carbonyl carbon of -NCO group is more electro positive because the aromatic ring drains the electron density of the nitrogen atom and this facilitates the blocking reaction. In the case of the aliphatic isocyanates, the carbonyl carbon is less electro positive and the nucleophile attack by the N-methylaniline is more difficult. Therefore, the use of catalyst is inevitable for the preparation of blocked isocyanates 3 and 7. Resu