铝酸钡与氢氧化钡脱硫过程比较.docVIP

铝酸钡与氢氧化钡脱硫过程比较 1,2，黎志英3，丁彤1,2 （1.贵州师范大学 材料与建筑工程学院，贵阳 550014；2.贵州省铝电解炭素材料工程技术研究中心，贵阳 550001；3.贵州大学 材料与冶金学院，贵阳 550003） 摘要：用铝酸钡和氢氧化钡对种分母液进行脱硫试验，对脱硫渣进行XRD分析，并比较脱硫过程。结果表明，氢氧化钡的脱硫效果更好，脱硫完时间更短，速率更快；铝酸钡先与碱液反应生成2BaO·Al2O3·5H2O，再与硫碱和碳碱反应，而氢氧化钡直接与硫碱和碳碱反应，脱硫过程均可用未反应核模型描述。 关键词：铝酸钡；氢氧化钡；种分母液；未反应核模型中图分类号：TF821 文献标识码：A 文章编号：1007-7545（2012）1-0000-00 Comparison?of?Barium Aluminate?and?Barium Hydroxide Desulfurization?Process ZHANG Nian-bing1,2, LI Zhi-ying3, DING Tong1,2 (1. College of Material and Civil Engineering, Guizhou Normal University, Guiyang 550001, China; 2. Guizhou Engineering Research Center for Carbon Materials of Aluminum Electrolytic, Guiyang 550001, China; 3. The Materials and Metallurgical College, Guizhou University, Guiyang 550003, China) Abstract: The seed precipitation liquor was desulfurized with barium aluminate?and?barium hydroxide respectively. The desulfurization?slag was characterized by XRD?analysis,?and the desulfurization?process was compared. The results show that barium hydroxide exceeds barium aluminate with better desulfurization in terms of effect, speed and?duration. In the desulfurization process with barium aluminate, 2BaO·Al2O3·5H2O is firstly produced in the reaction of barium aluminate with alkali, and then it reacts with sodium sulfate and sodium carbonate. To compare, Ba(OH)2·8H2O directly reacts with sodium sulfate and sodium carbonate in the desulfurization process with barium hydroxide. Both of desulfurization reaction processes can be described with “shrinking core model”. Key words: barium aluminate; barium hydroxide; desulfurization; seed precipitation liquor; shrinking core model 我国已探明的高硫型铝土矿中57.2%是高品位铝土矿[1-2]，在采用拜耳法生产氧化铝时需解决硫的危害。脱硫方法有浮选[3-4]、预焙烧[5-6]及湿法[7-12]等。湿法脱硫对铝酸钠溶液起到净化作用，提高生产能力，脱硫效果好，设备简单，环境污染小。但铝酸钡与氢氧化钡脱硫过程的行为至今仍不甚清楚，也鲜有研究报道。为此，本文铝酸钡与氢氧化钡对种分母液进行脱硫试验，脱硫过程进行比较。 1试验方法 1.1试验原料方法试验所用铝酸钡(烧结条件Al2O3/BaO1.1∶1，1 300 ℃，60 min)为验室合成，氢氧化钡为，均过筛。铝酸钠溶液为种分母液，硫含量用硫酸钠配制，种分母液成分 (g/L)：Al2O3 75.07、Na2OK 132.5、Na2Oc 19.44、Na2Os 9.06。搅拌速率可控恒温水浴锅