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Determination of 28 selected elements in textiles by axially viewed inductively coupled plasma optical emission spectrometry.pdf

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Determination of 28 selected elements in textiles by axially viewed inductively coupled plasma optical emission spectrometry.pdf

Talanta 83 (2011) 865–871 Contents lists available at ScienceDirect Talanta journal homepage: /locate/talanta Determination of 28 selected elements in textiles by axially viewed inductively coupled plasma optical emission spectrometry Iva Rezic′ a,b,?, Michaela Zeiner b, Ilse Steffan b a Laboratory of Analytical Chemistry, Department of Applied Chemistry, Faculty of Textile Technology, University of Zagreb, Croatia b Department of Analytical and Food Chemistry, Faculty of Chemistry, University of Vienna, Austria article info Article history: Received 7 June 2010 Received in revised form 27 September 2010 Accepted 26 October 2010 Available online 2 November 2010 Keywords: Validation Optimization ICP-OES Textile Microwave assisted digestion abstract A simple, robust and reliable analytical procedure for the determination of 28 selected elements, namely Al, As, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, K, Hg, Mg, Mn, Mo, Na, Ni, Pb, Sc, Si, Se, Sn, Sm, Sr, Tl, V, and Zn in textile materials by inductively coupled plasma optical emission spectrometry (ICP-OES) after microwave digestion of samples was optimized and validated in this work. The total amount of elements present in textile samples was determined after microwave digestion of materials in 7 mol/L nitric acid within the optimal working program: 5 min at 150 ?C (power 250 W), 15 min 180 ?C (300 W) and 20 min at the maximum temperature of 200 ?C (350 W). For the quality control reasons, which were ascertained by analysis of the certi?ed cotton trace elements reference material IAEA-V9, the ICP-OES method was optimized through several parameters: by comparing Meinhard and Gemcone Low Flow nebulizers ef?ciency, ranging nebulizer gas ?ows from 0.6 to 1.0 L/min, ranging sample ?ows from 0.8 to 1.2 mL/min, testing RF power from 1200 to 1400 W, detecting data acquisition time (read time) from 0 to 527 s, ranging washing (delay) time from 0 to 408 s, as well as by checking the occurring interferences for the optimal line sele