Morphology-controllable synthesis and thermal decomposition of Ag and Ni oxalate for Ag-Ni alloy electrical contact materials.pdfVIP

下载本文档

13
0
约3.52万字
约 8页
2017-03-16 发布于天津
举报
版权申诉

Morphology-controllable synthesis and thermal decomposition of Ag and Ni oxalate for Ag-Ni alloy electrical contact materials.pdf

1、本文档共8页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
8、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

Morphology-controllable synthesis and thermal decomposition of Ag and Ni oxalate for Ag-Ni alloy electrical contact materials.pdf

Materials and Design 108 (2016) 640–647 Contents lists available at ScienceDirect Materials and Design journal homepage: /locate/matdes Morphology-controllable synthesis and thermal decomposition of Ag and Ni oxalate for Ag-Ni alloy electrical contact materials Zhijie Lin a, Shaohong Liu a,b, Ji-Guang Li c,?, Jialin Chen b, Ming Xie b, Xiaodong Li a, Mu Zhang a, Qi Zhu a, Di Huo a, Xudong Sun a,d,?? a Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang, Liaoning 110819, China b State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China c Advanced Materials Processing Unit, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0044, Japan d School of Environmental and Chemical Engineering, Dalian University, Dalian, China HIGHLIGHTS ? Two Ag and Ni oxalate precursors (plates and particles) have been synthesized, and the formation mechanisms were investigated. ? Ag and Ni oxalate can thermal decompose into metallic Ag-Ni alloys at 400 °C in Ar, without further reduction in H2 gas. ? The sample reinforced by Ni plates shows a high electrical conductivity of 91.4 %IACS. ? The sample reinforced by dispersed nickel particles exhibits a better antiarc performance than that reinforced by Ni plates. GRAPHICAL ABSTRACT article info Article history: Received 6 May 2016 Received in revised form 26 June 2016 Accepted 28 June 2016 Available online 29 June 2016 Keywords: Ag-Ni alloys Morphology-controlled Thermal decomposition Electrical contact materials Anti-arc erosion abstract Two silver and nickel oxalate precursors with different morphologies (plates and particulates) were synthesized via precipitation of Ag+ and Ni2+ ions by C2O42?. In the case of high oxalate concentration and low pH value, the precursor was composed of Ag2C2O4 hexagonal plates with