异质结纳米光催化材料研究进展.pdfVIP

# 48 # 材料导报 A: 综述篇 2012 年 3 月( 上) 第 26 卷第 3 期 * 邱明艳1, 2 , 张天永2, 李 彬2 , 史慧贤2 (1 , 455000; 2 , 300072) 综述了近年来国内外异质结纳米光催化剂的 研究进展, 重点介 绍了异 质结纳 米光催化 剂的结 构特点 光催化机理及制备方法, 并简要分析了异质结纳米光催化剂存在 的问题和 未来发展 动向, 认为未 来异质 结纳米 光催 化剂的研究应集中在机理的深刻认识 光响应范围宽和量子效率高的催化剂的制备及异质结纳米光 催化技术工 程化 方面 Recent Research Progress on Heterostructure Nanophotocatalysts QIU M ingyan1, 2, ZH ANG T ianyong2 , L I Bin2, SH I H uixian2 ( 1 Department of Chemical and Environment Eng ineering, A nyang Institute of T echnolo g y, A nyang 455000; 2 Schoo l o f Chemical Eng ineering and T echno log y, T ianjin U niversit y, T ianjin 300072) Abstract T he r ecent dev elopment and pro gr ess of heter ostr ucture nano photo cat aly sts are rev iewed. T he str uctur al character istics, mechanisms and synthet ic metho ds of hetero st ructur e nanophotocatalysts are discussed. Some problems in t he cur rent study and the future trend of dev elo pment ar e brief ly analy zed. It is sug g ested that attent ion o f the future investig atio n on the heter ostructure nanophotocatalysts should focus on photo cata lyt ic mechanism, sy nthesis or pr epar atio n of novel heter ostructure nano photo cat aly st w ith wide response to lig ht and hig h photodeg radat ion quantum efficiency and eng ineering of heterostr ucture nanopho tocatalytic r eact ion. Key words photo cata lysis, het erostr ucture, nanometer , ,, Rauf[ 4] Rajeshw ar[ 1] , , [ 1- 3] , 1 ; , -1. 1 - n ( Wm) 1 , (Ws) , , : , n , 1( b) , , , Wm Ws , 2, , h+ , p n [ 5] , , , e- , - n , 1n ( Wm Ws ) Fig. 1 Energy- band diagram of metal and n-semiconduct ( Wm Ws ) * 国家高技术研究发展计划( 863 计划) ( 2006A A 06Z348) 邱明艳: 女, 1968 年生, 硕士 研究生, 副 教授 E- mail: ming yanqiu@ 163. com 授, 主要研究方向为纳米材料及光催化 E- mail: tyzhang @ tju. edu. cn 张天 永: 通讯作 者, 男, 1966 年生, 博 士生 导师, 教 异质结纳米光催化材料研究进展/ 邱明艳等 # 49 # 2n ( Wm Ws) Fig. 2 Energy-band diagram of metal and n-semiconductor( Wm Ws) 1. 2 3 p- n ,, , / 0 / 0, ,, , p- n ; 3 p-n Fig. 3 Energyband diagram of p-n heterojunction nanocatalyst 4 , , ( ), 4 n-