緩蚀剂复合MEA捕集CO2及缓蚀作用研究.docVIP

缓蚀剂复合MEA捕集CO2及缓蚀作用研究 袁龙1★，朱绎华2，刘建周2 （1.徐州医药高等职业学校，江苏 徐州 221116；2.中国矿业大学化工学院 , 江苏 徐州 221008） 摘要：乙醇胺(MEA)是一种常用的CO2吸收剂，具有较强的碱性和对金属的腐蚀性。在MEA捕集CO2溶液中加入钼酸钠、乙酸锌和乙二胺四醋酸四钠三种缓蚀剂进行改性研究，采用失重法研究了不同的缓蚀剂对60#钢的缓蚀性能。结合MEA吸收剂对CO2的吸收速率和吸收量的测试，通过正交试验筛选出适宜的复配缓蚀剂组成。结果表明：当复配缓蚀剂为60mg/L钼酸钠、5mg/L乙酸锌和20mg/L乙二胺四醋酸四钠时，吸收液对60#钢的缓蚀率为73.10%。与单一缓蚀剂相比，三种缓蚀剂复配使用具有更显著的缓蚀性能。高纯度的乙醇胺对碳钢的腐蚀性很小，但吸收CO2后腐蚀性增强。利用XRD测试出腐蚀产物主要是α-FeO(OH)，应用SEM观察了60#钢试片的表面形貌，根据测试结果探讨了腐蚀机理。 关键词：CO2；MEA；缓蚀剂；正交实验；SEM；XRD 中图分类号:X748?? Study on MEA removal CO2 Effect and inhibitive Efficiency of Complex Corrosion Inhibitors Yuan Long1 ，Zhu Yihua2，Liu Jianzhou 2 （Xuzhou Medical Higher Vocational School，Xuzhou Jiangsu 221116；School of Chemical Engineering and Technology, China Univ. of Mining Tech., Xuzhou 221008） Abstract: Ethanolamine (MEA), with a strong alkaline and corrosive to metal, is a common CO2 absorbent. Na2MoO4, Zn(OOCCH3)2 and EDTA-Na4 were added into the absorption liquid of MEA trapping CO2 to modify MEA?absorption?capability. Weight-loss method was used for studying different corrosion inhibitors on the corrosion performance of 60# steel. With testing absorption rate and capacity of MEA absorbing CO2, orthogonal experiment was used for selecting the suitable compositions of complex corrosion inhibitors. The results show that the inhibiting rate is 73.10% when the complex corrosion inhibitors are 60mg/L Na2MoO4, 5mg/L Zn(OOCCH3)2 and 20mg/L EDTA-Na4. Comparing with a single corrosion inhibitor, the absorption liquid of the three corrosion inhibitors has a more significant inhibition efficiency. The corrosion of MEA with a high purity to 60# steel is gently, but it becomes serious after MEA absorbing CO2. Corrosion products are mainly α-FeO(OH) by means of XRD. 60# steel surface morphology was tested by means of SEM to discuss the corrosion inhibition mechanism. Keywords: CO2; MEA; Corrosion Inhibitor; Orthogonal experiment; SEM; XRD 自工业革命以来，大气中CO2含量增加了37%，CO2的过度排放和减排已经成为全球面临的问题。政府间气候变化专门委员会(IPCC)预测[1]：从2002年到203