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Effect Mechanism of Polymer /Surfactant Combination Solution on Residual Oil
The Background
1. ASP combination solution flooding had been used in industrial field test in XXX Oilfield, the recovery was enhanced more than 12%.
2. The problems of ASP flooding
(1) The clay is dispersed and migrated;
(2) The alkali incrustation is formed;
(3) The viscoelasticity of polymer solution is reduced.
The main work
1. The influence of viscoelasticity of SP solution on recovery efficiency;
2. The influence of interfacial tension of SP solution on recovery efficiency;
3. The analysis of startup and migration mechanism of residual oil.
Oil Displacement Experiments on Visual Glass Models
1.1 Oil Displacement Experiments
In oil displacement experiments, glass etched model is used, the images of oil displacement process are translated into computer digital signal by the image collection system, the microscopic oil displacement process of SP solution is analyzed by the image analysis technology.
1.2 Chemicals
Polyacrylamide (PAM) is manufactured by Daqing
Reagent Factory and the average relative molecular
mass is 500×104 and 1600×104 separately.
(2) Surfactant is carboxyl betaine amphoteric surfactant
developed by ourselves. The structure of carboxyl
betaine is as follows:
Where R is alkyl or hydrocarbyl with long carbon chain.
SP
compound solution
Solution 1
Solution 2
Solution 3
HPAM
Relative molecule mass
500×104
1600×104
1600×104
Mass concentration
(mg/L)
1000
1000
1000
Content of surfactant (%)
0.025
0.025
0.200
Interfacial tension
(mN/m)
2.89×10-2
5.41×10-2
5.82×10-3
1.3 Composition and characteristic of SP compound solution
Table 1. Composition and interfacial tension of SP compound solution
2. The results and analysis of experiment
2.1 The influence of viscoelasticity
(a) Water Solution 1 (
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