污水处理厂尾水的电化学脱氮技术.pdfVIP

第64卷第3期 化工学报 V01．64 No．3 2013年3月 CIESC Journal March 2013 污水处理厂尾水的电化学脱氮技术 李德生1，范太兴1，申彦冰1，吴为中2 (1北京交通大学土木建筑工程学院，北京100044；2北京大学环境科学与工程学院，北京100871) 摘要：污水处理厂尾水中因可生物降解的有机物含量较低，无法实现生物深度脱氮，外排仍含有较高浓度的总 氮，若排入河流会引起富营养化，因此深入研究尾水的深度脱氮技术具有重要意义。采用催化电氧化技术，以 污水处理厂尾水为研究对象，研究了在电流密度、水力停留时间(HRT)、进水pH值等因素的影响下，尾水中 总氮的去除。结果表明，催化电氧化技术在电流密度为32．67 mA·cm～、进水pH值为6．25～7．02、HRT为 30 min时，总氮(TN)从26．40 mg·L_1降至11．9l mg·L ，N()f N从18．03 mg·L_1降至4．90 mg·L一， 去除率分别可达到54．9％和72．8％；TN的脱除主要以硝氮(NOa—N)的去除为主。催化电氧化技术能高效去 除污水厂尾水中的总氮，且具有运行稳定和抗冲击等优点。为污水处理厂尾水的电化学深度脱氮提供了理论 基础。 关键词：污水厂尾水；总氮；催化电氧化；硝氮 DOI：10．3969／j．issn．0438—1157．2013．03．042 中图分类号：X 703 文献标志码：A Electrochemical technology for 文章编号：0438—1157(2013)03—1084—07 denitrification of tail water from wastewater treatment plant LI Deshen91，FAN Taixin91，SHEN Yanbin91，WU Weizhon92 (1 School of Civil Engineering，Beijing Jiaotong University，Beijing 100044，China；2 College of Environmental Sciences and Engineering，Peking University，Beijing 100871，China) Abstract：It is difficult to achieve biological deep denitrification of wastewater due to lOW content of biodegradable organic matter in tail water from sewage treatment plant．If the tail water discharged into rivers，the eutrophication could be produced due to higher concentration of total nitrogen．Therefore，the study on deep denitrification technology is of important significance for tail water treatment．In this paper， the total nitrogen(TN)removal efficiency of a catalytic electric—oxidation technology and its influence factors，such as electric—current density，HRT，influent pH，etc．，were studied and analyzed．The results showed that total nitrogen can be decreased to 1 1．91 mg·I。～1 from 26．40 mg·L_1(54．9％)， NO；一N to 4．90 mg·L from 18．03 mg·L叫(72．8％)by the catalytic electric—oxidation technology at conditions of current density 32．67 mA·cm～，pH 6．25—7．02，and HRT 30 min．The N02一N removal is dominating in the TN removal of tail water from urban wastewater treatment plant．The results indicate that TN of tail water can be remove