有机机理习题.pptVIP

习题1（第1章-1） 习题2（第1章-2） 习题3（第1章-3） 习题4（第2章-2） 习题5（第3章-1） 习题6（第3章-2） 习题7（第5章） 习题8（第6章-2） 习题9（第7章-2） 习题10（第8章）;习题1;1.2 Explain each of the following observations;习题2;;习题3;;3.2 预测以下反应能否进行以及可能的产物;;;4.1. Calculate the activation parameters (?H? ?S?) at 80℃from the date given for the reaction shown below and explain the results of your calculation. ;4.2. The hydrolysis of benzoyl chloride was studied in the mixtures of water and acetone with different water content at 25oC. In all cases the reaction was first order with respect to benzoyl chloride. Calculate the activation entropies for the reaction in each mixture from the date of rate constants and activation energies given below. Why the activation entropy changes with water content? ;;习题5;若设H2NO3+、NO2+和PhHNO2+为活泼中间体，试建立稳态近似下的速率方程（以d[PhNO2]/dt表示），讨论速率方程的极端形式。 ;5.2. 苯炔与Z-二氯乙烯之间的加成反应按下述机理进行，生成顺式（C）和反式（T）产物的混合物：;a). 试求产物中顺式产物和反式产物的比例： Rcis=[C]/[T] b). 如果苯炔与E-二氯乙烯的反应也按相同的机理进行，试求产物中顺式产物和反式产物的比例： Rtrans=[C]/[T] c). 若Rcis=2.12, Rtrans=0.23, 计算k1/k2和k3/k-1 ;习题6;;6.2. 重氮盐（D+)与苯酚（N)生成偶氮染料（Az)的反应同时存在重氮盐的分解，反应过程如下： 当重氮盐和苯酚的起始浓度分别为[D+]0=1?10–4 mol L-1, [N]0= 1?10–2 mol L-1时，在273K下测得不同反应时间偶氮染料的浓度如下表。试用表中数据计算速率常数k2。 ;t/s;习题7;;7.2 Hydrolysis of ketene acetals takes place in acidic aqueous solution: On the basis of the following experimental results, postulate a mechanism which is consistent with all the data provided. Indicate the significance of each observation with respect to the mechanism you postulate. ;substrate;习题8;8.2 解释以下反应的位置选择性和机理;习题9;9.2 环庚酮有船式和椅式两种构象。实验发现，(+)-3-甲基环庚酮呈现负的Cotton效应。试推测环庚酮的优势构象。;9.3 预测下列化合物Cotton效应的符号 ;9.4 估算下列构象转化反应的平衡常数 ;习题10;10.2 When ketenes react with 1,3-dienes, bicyclic cyclobutanones are obtained. The mechanism of this reaction is usually described as a one-step [2+2] cycloaddition reaction, but the following two-step mechanism was recently proposed;(a) Name the two steps of the proposed mechanism.